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• W2334180611 endingPage "4569" @default.
• W2334180611 startingPage "4560" @default.
• W2334180611 abstract "Ligand L (2,6-bis{[7-(7-nitrobenzo[1,2,5]oxadiazole-4-yl)-3,10-dimethyl-1,4,7,10-tetraazacyclododeca-1-yl]methyl}phenol) is a fluorescent sensor that is useful for detecting Cu(II), Zn(II), and Cd(II). Some of the complexes formed are able to sense the presence of halides in solution. L passes through the cellular membrane, becoming fluorescent inside cells. The H–1L– species is able to form dinuclear complexes with [M2H–1L]3+ stoichiometry with Cu(II), Zn(II), and Cd(II) ions, experiencing a CHEF effect upon metal coordination in an acetonitrile/water 95:5 (v/v) solution. In all three of the complexes investigated, the metal cations are coordinatively unsaturated and can therefore bind secondary ligands as anionic species. The crystal structure of [Cd2(H–1L)Cl2](ClO4)·4H2O is discussed. The Zn(II) complex behaves as an OFF–ON sensor for fluoride and chloride anions." @default.
• W2334180611 created "2016-06-24" @default.
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• W2334180611 date "2014-04-23" @default.
• W2334180611 modified "2023-09-27" @default.
• W2334180611 title "Modulating the Sensor Response to Halide Using NBD-Based Azamacrocycles" @default.
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• W2334180611 doi "https://doi.org/10.1021/ic5001649" @default.
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