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• W2334185552 startingPage "1064" @default.
• W2334185552 abstract "Limiting partition coefficients (K-factors) of a selection of low-to-medium volatility solutes in biphasic 1-n-butyl-3-methylimidazolium trifluoromethanesulfonate ([bmim][TfO]) ionic liquid–supercritical carbon dioxide (IL–scCO2) system were obtained by capillary column supercritical fluid chromatography (SFC) with [bmim][TfO] as the stationary liquid and scCO2 as the carrier fluid. Solute selection included 24 compounds of diverse volatilities and chemical functionalities and the retention factors were measured within (313.2 to 353.2) K and (7.3 to 23.2) MPa. At a constant temperature, some pressure-tunable selectivity can be obtained through changes in the operating pressure and the scCO2 density. At a fixed temperature and density of CO2, solute partition coefficients were correlated in terms of Abraham’s linear solvation energy relationships. Compared to our previous studies with other ILs ([hmim][Tf2N], [bmim][MeSO4], and [thtdp][Cl]), the loss of [bmim][TfO] from the column during the experimental run was markedly lower in the present work." @default.
• W2334185552 created "2016-06-24" @default.
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• W2334185552 date "2012-03-08" @default.
• W2334185552 modified "2023-09-30" @default.
• W2334185552 title "Solute Partitioning Between 1-<i>n</i>-Butyl-3-methylimidazolium Trifluoromethanesulfonate Ionic Liquid and Supercritical CO₂" @default.
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• W2334185552 doi "https://doi.org/10.1021/je200986x" @default.
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