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- W2334194892 abstract "Temperature dependencies of the 1 H and 19 F NMR spectra of a mixture of paramagnetic complexes [Tm(H 2 O)(ptf) 3 ] (I), [Tm(ptf) 3 ] × (H 2 O) (II) and [Tm 2 (ptf) 6 ] (III) have been analyzed. The activation free energy (ΔG ≠ (298)) of the exchange between I and II is 55 ± 3 kJ/mol. Coordination compounds I and III may serve as the most sensitive 1 H and 19 F NMR lanthanide paramagnetic probes for in situ temperature control in solutions." @default.
- W2334194892 created "2016-06-24" @default.
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- W2334194892 date "2016-10-01" @default.
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- W2334194892 title "Thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature" @default.
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- W2334194892 doi "https://doi.org/10.1016/j.snb.2016.04.009" @default.
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