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• W2334199461 abstract "DNA sequences that undergo large changes in secondary structure upon binding of small molecules are the basis for molecular switches. Here we report a Zn2+ complex that promotes the conversion of a fully complementary DNA double helix into DNA hairpins. The conformational switch is promoted by an isolated Zn2+ complex or by free ZnCl2 and a macrocyclic ligand. The switch is selective for Zn2+ over biologically relevant transition-metal ions including Cu2+ and Fe2+. The dual ligand/DNA switch is an approach that may improve the selectivity for metal-ion-sensing applications." @default.
• W2334199461 created "2016-06-24" @default.
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• W2334199461 date "2015-03-09" @default.
• W2334199461 modified "2023-10-06" @default.
• W2334199461 title "Zn²⁺-Selective Switch of Duplex to Hairpin DNA" @default.
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• W2334199461 doi "https://doi.org/10.1021/ic503074p" @default.
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