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- W2334201323 abstract "Poly(ethylene glycol)-block-poly(partially benzyl-esterified aspartic acid), denoted by PEG-P(Asp(Bzl)), is one of the most examined blockcopolymers for drug carriers. However, little is known about fundamental physical properties. Nine samples of PEG-P(Asp(Bzl)) with different benzylation fractions (FBzl) and aspartic chain lengths (DPAsp) were synthesized, and the aggregation number (Nagg), core radius (RC), and other structural parameters were determined with combination of light scattering and synchrotron X-ray small-angle scattering. The major factor to determine Nagg and RC was found to be FBzl, i.e., the hydrophobic nature of the core, even though FBzl was changed in the relatively small composition range from 66 to 89 mol %. When we compared the data for the same FBzl, the scaling theory was consistent with the core chain length dependence of both core and micelle sizes. The overcrowding nature of the tethered PEG chains on the micelles was increased about 1.3–2.9 times with increasing Nagg compared with the unperturbed state in solutions." @default.
- W2334201323 created "2016-06-24" @default.
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- W2334201323 date "2012-07-06" @default.
- W2334201323 modified "2023-10-03" @default.
- W2334201323 title "Composition Dependence of the Micellar Architecture Made from Poly(ethylene glycol)-<i>block</i>-Poly(partially benzyl-esterified aspartic acid)" @default.
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- W2334201323 doi "https://doi.org/10.1021/jp300936d" @default.
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