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• W2334235863 abstract "In situ x-ray absorption spectroscopy (XAS) in 1 M HC1O4 was used to examine the electronic and structural effects of hydrogen adsorption on carbon supported Pt (Pt/C) and Pt alloyed with first row transition metals (Cr, Mn, Fe, Co, and Ni). In the case of Pt/C, potential excursions from the double layer region (0.54 V vs. RHE) to 0.0 V caused significant changes in the XAS spectra whereas none was observed for the alloys. The L, and L2 x-ray absorption near edge structure indicated the generation of empty electronic states in the vicinity of the Fermi level due to adsorption of hydrogen, and the L, extended x-ray absorption fine structure indicated an increase in the coordination number of the first Pt-Pt" @default.
• W2334235863 created "2016-06-24" @default.
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• W2334235863 date "1996-01-01" @default.
• W2334235863 modified "2023-09-27" @default.
• W2334235863 title "Hydrogen Electrocatalysis by Carbon Supported Pt and Pt Alloys An In Situ X-Ray Absorption Study" @default.
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• W2334235863 hasPublicationYear "1996" @default.
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