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• W2334244878 abstract "We investigate the effect of Rh doping in Sr2IrO4 using X-ray absorption spectroscopy (XAS). We observed appearance of new electron-addition states with increasing Rh concentration (x in Sr2Ir1-xRhxO4) in accordance with the concept of hole doping. The intensity of the hole-induced state is however weak, suggesting weakness of charge transfer (CT) effect and Mott insulating ground states. Also, Ir Jeff = 1/2 upper Hubbard band shifts to lower energy as x increases up to x = 0.23. Combined with optical spectroscopy, these results suggest a hybridisation-related mechanism, in which Rh doping can weaken the (Ir Jeff = 1/2)-(O 2p) orbital hybridisation in the in-planar Rh-O-Ir bond networks." @default.
• W2334244878 created "2016-06-24" @default.
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• W2334244878 date "2016-03-30" @default.
• W2334244878 modified "2023-10-17" @default.
• W2334244878 title "X-ray Absorption Spectroscopy Study of the Effect of Rh doping in Sr2IrO4" @default.
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• W2334244878 doi "https://doi.org/10.1038/srep23856" @default.
• W2334244878 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4812298" @default.
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