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- W2334251112 abstract "Novel ruthenium−amidinate complexes, (η6-C6H5R)Ru(η2-amidinate)X (R = Me, OMe, F) (4) and [Ru(η2-amidinate)(MeCN)4]+PF6- (5) are synthesized by photochemical displacement of the benzene ligand in (η6-C6H6)Ru(η2-amidinate)X (3) by arenes or MeCN. The acetonitrile ligands of 5 are easily replaceable by other σ-donor ligands (L) such as pyridines, phosphines, and isocyanides to afford the corresponding derivatives, [Ru(η2-amidinate)(MeCN)n(L)4-n+]PF6- (n = 1 or 2)." @default.
- W2334251112 created "2016-06-24" @default.
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- W2334251112 date "2002-08-16" @default.
- W2334251112 modified "2023-10-16" @default.
- W2334251112 title "Access to Novel Ruthenium−Amidinate Complexes, (η<sup>6</sup>-arene)Ru(η<sup>2</sup>-amidinate)X and [Ru(η<sup>2</sup>-amidinate)(MeCN)<sub>4</sub>]<sup>+</sup>PF<sub>6</sub><sup>-</sup> by Photochemical Displacement of the Benzene Ligand in (η<sup>6</sup>-C<sub>6</sub>H<sub>6</sub>)Ru(η<sup>2</sup>-amidinate)X" @default.
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- W2334251112 doi "https://doi.org/10.1021/om020227y" @default.
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