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- W2334285410 endingPage "6663" @default.
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- W2334285410 abstract "Thermochromic emission shifts of 4-aminophthalimide (4-AP) dissolved in three 1-chloroalkanes, namely, 1-chloropropane, 1-chlorobutane, and 1-chlorohexane, together with fluorescence decays measured at different wavelengths, all solvents containing different small amounts of water (10–4–10–2 M), are reported in a broad temperature range covering the bulk water melting point. Our studies have shown that 4-AP is an effective indicator of water presence even at concentrations given by solvent suppliers for so-called “dry” solvents. Additionally, indications of water ice-clusters formation in 1-chloroalkanes, starting at different temperatures depending on water concentration, have been found. Finally, 4-AP in 1-chloroalkane + water mixture is shown to present at different temperatures three basic types of sources of time-resolved emission spectra (TRES) time/spectral evolution: emission of two kinetically coupled species, solvent relaxation, and simultaneous emission of two independent species." @default.
- W2334285410 created "2016-06-24" @default.
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- W2334285410 creator A5068177275 @default.
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- W2334285410 date "2012-06-13" @default.
- W2334285410 modified "2023-10-17" @default.
- W2334285410 title "Temperature Influence on 4-Aminophthalimide Emission in 1-Chloroalkanes Plus Water Mixtures" @default.
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- W2334285410 doi "https://doi.org/10.1021/jp302373j" @default.
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