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• W2334288529 startingPage "7369" @default.
• W2334288529 abstract "UV irradiation of TiO(2) nanoparticles in the presence of Ag(+) ions results in the quantitative reduction and deposition of silver on its surface. Continued UV irradiation following the deposition of Ag on the TiO(2) surface causes a blue shift in the surface plasmon peak from 430 to 415 nm as these particles become charged with excess electrons. Under UV irradiation, both the charging and discharging of electrons occur at different rates, thus allowing the system to attain a steady state. Upon stopping the UV irradiation, a fraction of these electrons remain stored. The electron storage is dependent on the amount of Ag deposited on TiO(2) nanoparticles with maximum capacity seen at 8.6 μM of Ag in a suspension containing 5.8 mM of TiO(2). Such electron charging and discharging processes in semiconductor-metal composites need to be taken into account while evaluating the plasmon resonance induced effects in photocatalysis and photoelectrochemistry." @default.
• W2334288529 created "2016-06-24" @default.
• W2334288529 creator A5015818129 @default.
• W2334288529 creator A5061425161 @default.
• W2334288529 date "2011-08-12" @default.
• W2334288529 modified "2023-10-01" @default.
• W2334288529 title "Capture, Store, and Discharge. Shuttling Photogenerated Electrons across TiO₂–Silver Interface" @default.
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• W2334288529 doi "https://doi.org/10.1021/nn202294b" @default.
• W2334288529 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21819038" @default.
• W2334288529 hasPublicationYear "2011" @default.
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