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- W2334295302 abstract "The facilitated ion transfer (FIT) of uranyl or dioxouranium (UO(2)(2+)) was studied electrochemically using a micro interface between two immiscible electrolytic solutions (micro-ITIES) in order to evaluate the complexation stoichiometry and complexation constants (β) of two widely used ligands in spent fuel reprocessing: tributylphosphate (TBP) and octyl(phenyl)-N,N-diisobutylcarbamoylmethyl-phosphine oxide (CMPO). For the first time, discrete interfacial complexation reaction steps of varying uranyl to the two ligands ratios were resolved using the micro-ITIES hosted at the tip of a 25 μm diameter glass capillary. Two stoichiometries for UO(2)NO(3)TBP(n)(+) were determined including n = 3 and 4 with β values of 3.2 × 10(11) and 3.9 × 10(13), respectively. Subsequently, three distinct complexation reactions of CMPO with UO(2)(2+) were discovered corresponding to UO(2)NO(3)CMPO(2)(+), UO(2)NO(3)CMPO(3)(+), and UO(2)CMPO(5)(2+) whose respective complexation constants were determined to be 8.0 × 10(11), 8.8 × 10(14), and 6.5 × 10(32). The participation of nitrate anions in these complexation reactions is also discussed." @default.
- W2334295302 created "2016-06-24" @default.
- W2334295302 creator A5022602287 @default.
- W2334295302 creator A5044461492 @default.
- W2334295302 date "2011-09-01" @default.
- W2334295302 modified "2023-10-14" @default.
- W2334295302 title "Uranyl Ion Extraction with Conventional PUREX/TRUEX Ligands Assessed by Electroanalytical Chemistry at Micro Liquid/Liquid Interfaces" @default.
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- W2334295302 doi "https://doi.org/10.1021/ac2018684" @default.
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