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- W2334343038 abstract "Effective hydrogen production is achieved via steam reforming of the oxygenated hydrocarbons, including methanol and dimethyl ether, over Cu-based spinel-oxide catalysts. CuFe2O4, CuMn2O4, and CuCr2O4 were well-crystallized in spinel structures and were provided with low specific surface areas below 2 m2 g–1. Upon reduction, the spinels possessed Cu+-rich surfaces when compared with a commercial Cu/ZnO/Al2O3, which resulted in better catalytic performance in methanol steam reforming (MSR). The composite catalysts of the Cu spinel and γ-Al2O3 were promising for dimethyl ether steam reforming (DMESR) in terms of activity, selectivity, and stability. The descending order of the DMESR activity over the composite catalysts was as follows: CuFe2O4–γ-Al2O3 > CuMn2O4–γ-Al2O3 > CuCr2O4–γ-Al2O3, which was in line with the MSR activity over Cu–spinel catalysts. This revealed that the MSR activity strongly contributed to the high DMESR activity using the composite Cu–spinel catalysts and γ-Al2O3. The theoretical calculations demonstrated that the observed MSR reactivity trend follows the reactivity of the MSR rate-limiting step of methoxy dehydrogenation. The required active sites are shown to be both Cu and metal oxide in the facilitation of methoxy dehydrogenation." @default.
- W2334343038 created "2016-06-24" @default.
- W2334343038 creator A5010033097 @default.
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- W2334343038 date "2013-10-31" @default.
- W2334343038 modified "2023-10-17" @default.
- W2334343038 title "Cu–Cr, Cu–Mn, and Cu–Fe Spinel-Oxide-Type Catalysts for Reforming of Oxygenated Hydrocarbons" @default.
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- W2334343038 doi "https://doi.org/10.1021/jp407717c" @default.
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