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- W2334351802 abstract "Bis (carboxyphenyl) disulfide is very readily hydrolysed with aqueous alkali hydroxide at room temperature. Simultaneous oxidation and reduction take place and m-thiobenzoic acid is obtaind as the reduction product. Examination of this reaction showed that the disulfoxide, which Smiles reported as the oxidation product, did not exist, but that m-sulfinobenzoic acid was found as the oxidation product. Furthrer, hydrolysis of many aromatic disulfide was examind. The disulfides which were soluble in aqueous alkali hydroxide, except the ortho-substituted compounds, were hydrolysed in the same manner as the above compound. The mechanism of hydrolysis with alcoholic alkali hydroxide seems to be different." @default.
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- W2334351802 date "1968-01-01" @default.
- W2334351802 modified "2023-09-26" @default.
- W2334351802 title "Mechanism of Hydrolysis of Aromatic Disulfide with Alkali Hydroxide Solution. I. : Hydrolysis of Aromatic Disulfide with Alkali Hydroxide Solution" @default.
- W2334351802 doi "https://doi.org/10.1248/yakushi1947.88.2_145" @default.
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