Matches in SemOpenAlex for { <https://semopenalex.org/work/W2334367910> ?p ?o ?g. }
- W2334367910 endingPage "8362" @default.
- W2334367910 startingPage "8355" @default.
- W2334367910 abstract "A facile synthetic route to a new polycyclic pyrrole derivative, 3,8-diethyl-1,10-dihydro-benzo[e]pyrrolo[3,2-g]indole (1), is reported. This annulated bipyrrole acts as a monomer for electropolymerization and forms an electrochromic conducting polymer (poly1) when electrooxidized at low potentials (0.4 V vs Ag/Ag(+)) in acetonitrile. The presence of alkyl substituents at the 3 and 8 carbons (β-pyrrolic positions) induces regioselective 2,5'-coupling of the pyrrole repeat units and gives rise to the more uniform polymeric product, poly1. Poly1 exhibits globular morphology, as judged from SEM pictures. Its spectroelectrochemical features can be attributed to the formation of four possible states: neutral, polaron, bipolaron, and transverse bipolaron. The relatively low switching potentials (-0.6 to +0.9 V vs Ag/Ag(+) in MeCN) displayed by poly1 leads us to suggest that 1 has a role to play as a polymerizable moiety for the development of multicolor electrochromic materials." @default.
- W2334367910 created "2016-06-24" @default.
- W2334367910 creator A5000215293 @default.
- W2334367910 creator A5002718139 @default.
- W2334367910 creator A5006693483 @default.
- W2334367910 creator A5038322271 @default.
- W2334367910 creator A5051391205 @default.
- W2334367910 creator A5084416976 @default.
- W2334367910 date "2010-11-19" @default.
- W2334367910 modified "2023-09-23" @default.
- W2334367910 title "Naphthobipyrrole: Versatile Synthesis and Electropolymerization" @default.
- W2334367910 cites W1977223122 @default.
- W2334367910 cites W1978863181 @default.
- W2334367910 cites W1981525805 @default.
- W2334367910 cites W1989871025 @default.
- W2334367910 cites W1990477411 @default.
- W2334367910 cites W1996436854 @default.
- W2334367910 cites W1998359432 @default.
- W2334367910 cites W2000459497 @default.
- W2334367910 cites W2000815001 @default.
- W2334367910 cites W2028152369 @default.
- W2334367910 cites W2031837802 @default.
- W2334367910 cites W2032660821 @default.
- W2334367910 cites W2038992965 @default.
- W2334367910 cites W2040599106 @default.
- W2334367910 cites W2055499045 @default.
- W2334367910 cites W2060975776 @default.
- W2334367910 cites W2065959255 @default.
- W2334367910 cites W2069035554 @default.
- W2334367910 cites W2073604438 @default.
- W2334367910 cites W2075694935 @default.
- W2334367910 cites W2076573707 @default.
- W2334367910 cites W2083228173 @default.
- W2334367910 cites W2089828074 @default.
- W2334367910 cites W2104578329 @default.
- W2334367910 cites W2124437050 @default.
- W2334367910 cites W2131933593 @default.
- W2334367910 cites W2952207521 @default.
- W2334367910 cites W4298046541 @default.
- W2334367910 doi "https://doi.org/10.1021/jo1016426" @default.
- W2334367910 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21090640" @default.
- W2334367910 hasPublicationYear "2010" @default.
- W2334367910 type Work @default.
- W2334367910 sameAs 2334367910 @default.
- W2334367910 citedByCount "26" @default.
- W2334367910 countsByYear W23343679102012 @default.
- W2334367910 countsByYear W23343679102013 @default.
- W2334367910 countsByYear W23343679102014 @default.
- W2334367910 countsByYear W23343679102015 @default.
- W2334367910 countsByYear W23343679102016 @default.
- W2334367910 countsByYear W23343679102017 @default.
- W2334367910 countsByYear W23343679102018 @default.
- W2334367910 countsByYear W23343679102019 @default.
- W2334367910 countsByYear W23343679102021 @default.
- W2334367910 countsByYear W23343679102022 @default.
- W2334367910 crossrefType "journal-article" @default.
- W2334367910 hasAuthorship W2334367910A5000215293 @default.
- W2334367910 hasAuthorship W2334367910A5002718139 @default.
- W2334367910 hasAuthorship W2334367910A5006693483 @default.
- W2334367910 hasAuthorship W2334367910A5038322271 @default.
- W2334367910 hasAuthorship W2334367910A5051391205 @default.
- W2334367910 hasAuthorship W2334367910A5084416976 @default.
- W2334367910 hasConcept C101643646 @default.
- W2334367910 hasConcept C106159729 @default.
- W2334367910 hasConcept C111771559 @default.
- W2334367910 hasConcept C121332964 @default.
- W2334367910 hasConcept C133495861 @default.
- W2334367910 hasConcept C147120987 @default.
- W2334367910 hasConcept C147789679 @default.
- W2334367910 hasConcept C161790260 @default.
- W2334367910 hasConcept C162324750 @default.
- W2334367910 hasConcept C166940927 @default.
- W2334367910 hasConcept C17525397 @default.
- W2334367910 hasConcept C178790620 @default.
- W2334367910 hasConcept C185592680 @default.
- W2334367910 hasConcept C188027245 @default.
- W2334367910 hasConcept C21951064 @default.
- W2334367910 hasConcept C2776568683 @default.
- W2334367910 hasConcept C2777463227 @default.
- W2334367910 hasConcept C2779400197 @default.
- W2334367910 hasConcept C2779546866 @default.
- W2334367910 hasConcept C2780263894 @default.
- W2334367910 hasConcept C2781436544 @default.
- W2334367910 hasConcept C521977710 @default.
- W2334367910 hasConcept C59759590 @default.
- W2334367910 hasConcept C62520636 @default.
- W2334367910 hasConcept C64127065 @default.
- W2334367910 hasConcept C71240020 @default.
- W2334367910 hasConcept C75473681 @default.
- W2334367910 hasConceptScore W2334367910C101643646 @default.
- W2334367910 hasConceptScore W2334367910C106159729 @default.
- W2334367910 hasConceptScore W2334367910C111771559 @default.
- W2334367910 hasConceptScore W2334367910C121332964 @default.
- W2334367910 hasConceptScore W2334367910C133495861 @default.
- W2334367910 hasConceptScore W2334367910C147120987 @default.
- W2334367910 hasConceptScore W2334367910C147789679 @default.
- W2334367910 hasConceptScore W2334367910C161790260 @default.
- W2334367910 hasConceptScore W2334367910C162324750 @default.