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- W2334372334 abstract "We used a variety of optical probes to investigate the triplet excitons of a platinum containing ensuremath{pi}-conjugated polymer (Pt1) having large spin-orbit interaction, in the form of films and solid state solutions. The optical probes include absorption, photoinduced absorption, and emission spectroscopy and their corresponding dynamics, as well as their excitation dependencies. We found that the intensity of the 0-0 line in the vibrationally resolved phosphorescence emission spectrum anomalously increases at low temperatures in Pt1 films, but less so in Pt1 solid state solutions, or when using below-gap excitation. Making use of the measured Raman scattering spectrum we analyze the vibration progression in the phosphorescence spectrum, and conclude that the increase in the 0-0 line intensity is due to triplet excitons that interact coherently at low temperatures, giving rise to phosphorescence superradiance." @default.
- W2334372334 created "2016-06-24" @default.
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- W2334372334 date "2012-11-05" @default.
- W2334372334 modified "2023-10-16" @default.
- W2334372334 title "Phosphorescence superradiance in a Pt-containing<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>π</mml:mi></mml:math>-conjugated polymer" @default.
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- W2334372334 doi "https://doi.org/10.1103/physrevb.86.195203" @default.
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