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- W2334384803 abstract "A vanadium–binaphthylbishydroxamic acid (BBHA) complex-catalyzed asymmetric epoxidation of allylic alcohols is described. The optically active binaphthyl-based ligands BBHA 2a and 2b were synthesized from (S)-1,1′-binaphthyl-2,2′-dicarboxylic acid and N-substituted-O-trimethylsilyl (TMS)-protected hydroxylamines via a one-pot, three-step procedure. The epoxidations of 2,3,3-trisubstituted allylic alcohols using the vanadium complex of 2a were easily performed in toluene with a TBHP water solution to afford (2R)-epoxy alcohols in good to excellent enantioselectivities." @default.
- W2334384803 created "2016-06-24" @default.
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- W2334384803 date "2015-03-06" @default.
- W2334384803 modified "2023-09-27" @default.
- W2334384803 title "Asymmetric Epoxidation of Allylic Alcohols Catalyzed by Vanadium–Binaphthylbishydroxamic Acid Complex" @default.
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- W2334384803 doi "https://doi.org/10.1021/acs.joc.5b00185" @default.
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