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- W2334451440 endingPage "315" @default.
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- W2334451440 abstract "Single-pulse pulsed-laser polymerization in conjunction with time-resolved quantitative EPR detection of radicals, SP−PLP−EPR, has been carried out in the early period of styrene polymerizations between 73 and 135 °C using dicumyl peroxide as the photoinitiator. To enhance signal-to-noise quality, in addition to styrene-H8, the fully deuterated monomer, Sty-d8, has been investigated. The chain-length dependence of the rate coefficient for termination of two radicals of chain length i, kti,i, is adequately represented by the composite model. The power-law exponents for short-chain and long-chain radicals are obtained as αs = 0.51 ± 0.05 and αl = 0.16 ± 0.05, respectively, with the two ranges being separated by the crossover chain length, ic = 30 ± 10. The termination rate coefficient for two radicals of chain length unity, kt1,1, scales with temperature as does monomer fluidity. From kti,i deduced via SP−PLP−EPR, chain-length-averaged termination rate coefficients, ⟨kt⟩, have been estimated, which are close to the reported experimental values." @default.
- W2334451440 created "2016-06-24" @default.
- W2334451440 creator A5014443257 @default.
- W2334451440 creator A5055116080 @default.
- W2334451440 date "2015-01-13" @default.
- W2334451440 modified "2023-10-16" @default.
- W2334451440 title "Chain-Length-Dependent Termination of Styrene Bulk Homopolymerization Studied by SP−PLP−EPR" @default.
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- W2334451440 doi "https://doi.org/10.1021/ma5022665" @default.
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