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- W2334476009 abstract "In this work, we demonstrated that (i) salts of RNA/DNA segments were capable of catalyzing Knoevenagel condensation at physiological pH 7.0 with efficiency comparable to one of the best enzymes, porcine pancreatic lipase (PPL); and (ii) a broad scope of substrates could be successfully used in this reaction. Velocity of catalysis was positively correlated with the content of GC nucleosides in DNA/RNA; while the 3D-organization in DNA segments largely contributed to the elevated turnover number of catalysis. An insight into the reaction mechanism (based on quantitative analysis of kinetics) elucidated general similarities between DNA, RNA, and PPL in the substrate binding mechanisms." @default.
- W2334476009 created "2016-06-24" @default.
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- W2334476009 date "2014-08-27" @default.
- W2334476009 modified "2023-10-16" @default.
- W2334476009 title "Kinetic Insights of DNA/RNA Segment Salts Catalyzed Knoevenagel Condensation Reaction" @default.
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- W2334476009 doi "https://doi.org/10.1021/cs500882r" @default.
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