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- W2334563886 abstract "The factors determining diastereoselectivity observed in the multicomponent conversion of amino acids, aziridine aldehyde dimers, and isocyanides into chiral piperazinones have been investigated. Amino acid-dependent selectivity for either trans- or cis-substituted piperazinone products has been achieved. An experimentally determined diastereoselectivity model for the three-component reaction driven by aziridine aldehyde dimers has predictive value for different substrate classes. Moreover, this model is useful in reconciling the previously reported observations in multicomponent reactions between isocyanides, α-amino acids, and monofunctional aldehydes." @default.
- W2334563886 created "2016-06-24" @default.
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- W2334563886 date "2014-10-22" @default.
- W2334563886 modified "2023-10-16" @default.
- W2334563886 title "Stereocontrolled Disruption of the Ugi Reaction toward the Production of Chiral Piperazinones: Substrate Scope and Process Development" @default.
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- W2334563886 doi "https://doi.org/10.1021/jo5018316" @default.
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