FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2334602880> ?p ?o ?g. }

• W2334602880 endingPage "651" @default.
• W2334602880 startingPage "641" @default.
• W2334602880 abstract "UV–vis steady-state and time-resolved techniques were employed to study the excited-state proton-transfer process from two weak photoacids positioned next to the surface of chitosan and cellulose. Both chitosan and cellulose are linear polysaccharides; chitosan is composed mainly of d-glucosamine units. In order to overcome the problem of the high basicity of the glucosamine, we chose 2-naphthol (pKa* ≈ 2.7) and 2-naphthol-6-sulfonate (pKa* ≈ 1.7) as the proton emitters because of their ground state pKa (≈9). Next to the 1:1 cellulose:water weight ratio, the ESPT rate of these photoacids is comparable to that of bulk water. We found that the ESPT rate of 2-naphthol (2NP) and 2-naphthol-6-sulfonate (2N6S) next to chitosan in water (1:1) weight ratio samples is higher than in bulk water by a factor of about 5 and 2, respectively. We also found an efficient ESPT process that takes place from these photoacids in the methanol environment next to the chitosan scaffold, whereas ESPT is not observed in methanolic bulk solutions of these photoacids. We therefore conclude that ESPT occurs from these photoacids to the d-glucosamine units that make up chitosan." @default.
• W2334602880 created "2016-06-24" @default.
• W2334602880 creator A5074138139 @default.
• W2334602880 creator A5084003851 @default.
• W2334602880 date "2015-01-16" @default.
• W2334602880 modified "2023-09-27" @default.
• W2334602880 title "Excited-State Proton Transfer of Weak Photoacids Adsorbed on Biomaterials: Proton Transfer to Glucosamine of Chitosan" @default.
• W2334602880 cites W1967325672 @default.
• W2334602880 cites W1969876717 @default.
• W2334602880 cites W1980331560 @default.
• W2334602880 cites W1983486851 @default.
• W2334602880 cites W1987221174 @default.
• W2334602880 cites W1992443273 @default.
• W2334602880 cites W1992718766 @default.
• W2334602880 cites W1994596332 @default.
• W2334602880 cites W1996487645 @default.
• W2334602880 cites W2013570914 @default.
• W2334602880 cites W2014966337 @default.
• W2334602880 cites W2020999936 @default.
• W2334602880 cites W2031745724 @default.
• W2334602880 cites W2043626482 @default.
• W2334602880 cites W2048379858 @default.
• W2334602880 cites W2053304852 @default.
• W2334602880 cites W2066279026 @default.
• W2334602880 cites W2073464189 @default.
• W2334602880 cites W2079053731 @default.
• W2334602880 cites W2080377208 @default.
• W2334602880 cites W2088256588 @default.
• W2334602880 cites W2130032175 @default.
• W2334602880 cites W2139413502 @default.
• W2334602880 cites W2152414522 @default.
• W2334602880 cites W4243897536 @default.
• W2334602880 doi "https://doi.org/10.1021/jp511349j" @default.
• W2334602880 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25556376" @default.
• W2334602880 hasPublicationYear "2015" @default.
• W2334602880 type Work @default.
• W2334602880 sameAs 2334602880 @default.
• W2334602880 citedByCount "14" @default.
• W2334602880 countsByYear W23346028802015 @default.
• W2334602880 countsByYear W23346028802016 @default.
• W2334602880 countsByYear W23346028802017 @default.
• W2334602880 countsByYear W23346028802018 @default.
• W2334602880 countsByYear W23346028802019 @default.
• W2334602880 countsByYear W23346028802020 @default.
• W2334602880 countsByYear W23346028802021 @default.
• W2334602880 crossrefType "journal-article" @default.
• W2334602880 hasAuthorship W2334602880A5074138139 @default.
• W2334602880 hasAuthorship W2334602880A5084003851 @default.
• W2334602880 hasConcept C100817775 @default.
• W2334602880 hasConcept C121332964 @default.
• W2334602880 hasConcept C127413603 @default.
• W2334602880 hasConcept C150394285 @default.
• W2334602880 hasConcept C178790620 @default.
• W2334602880 hasConcept C181500209 @default.
• W2334602880 hasConcept C185544564 @default.
• W2334602880 hasConcept C185592680 @default.
• W2334602880 hasConcept C2778125326 @default.
• W2334602880 hasConcept C2779251873 @default.
• W2334602880 hasConcept C2779607525 @default.
• W2334602880 hasConcept C2779732960 @default.
• W2334602880 hasConcept C42360764 @default.
• W2334602880 hasConcept C54516573 @default.
• W2334602880 hasConcept C62520636 @default.
• W2334602880 hasConcept C75473681 @default.
• W2334602880 hasConceptScore W2334602880C100817775 @default.
• W2334602880 hasConceptScore W2334602880C121332964 @default.
• W2334602880 hasConceptScore W2334602880C127413603 @default.
• W2334602880 hasConceptScore W2334602880C150394285 @default.
• W2334602880 hasConceptScore W2334602880C178790620 @default.
• W2334602880 hasConceptScore W2334602880C181500209 @default.
• W2334602880 hasConceptScore W2334602880C185544564 @default.
• W2334602880 hasConceptScore W2334602880C185592680 @default.
• W2334602880 hasConceptScore W2334602880C2778125326 @default.
• W2334602880 hasConceptScore W2334602880C2779251873 @default.
• W2334602880 hasConceptScore W2334602880C2779607525 @default.
• W2334602880 hasConceptScore W2334602880C2779732960 @default.
• W2334602880 hasConceptScore W2334602880C42360764 @default.
• W2334602880 hasConceptScore W2334602880C54516573 @default.
• W2334602880 hasConceptScore W2334602880C62520636 @default.
• W2334602880 hasConceptScore W2334602880C75473681 @default.
• W2334602880 hasFunder F4320320878 @default.
• W2334602880 hasFunder F4320322252 @default.
• W2334602880 hasIssue "4" @default.
• W2334602880 hasLocation W23346028801 @default.
• W2334602880 hasLocation W23346028802 @default.
• W2334602880 hasOpenAccess W2334602880 @default.
• W2334602880 hasPrimaryLocation W23346028801 @default.
• W2334602880 hasRelatedWork W1984891107 @default.
• W2334602880 hasRelatedWork W2013502562 @default.
• W2334602880 hasRelatedWork W2039954703 @default.
• W2334602880 hasRelatedWork W2364024083 @default.
• W2334602880 hasRelatedWork W2748952813 @default.
• W2334602880 hasRelatedWork W306614973 @default.
• W2334602880 hasRelatedWork W3151542123 @default.
• W2334602880 hasRelatedWork W3188145067 @default.
• W2334602880 hasRelatedWork W4286111267 @default.
• W2334602880 hasRelatedWork W4294845532 @default.
• W2334602880 hasVolume "119" @default.

• next