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• W2334631784 startingPage "6676" @default.
• W2334631784 abstract "Microorganisms can strongly influence the chemical and physical properties of the subsurface. Changes in microbial activity caused by geological CO2 storage, therefore, have the potential to influence the capacity, injectivity, and integrity of CO2 storage reservoirs and ultimately the environmental impact of CO2 injection. This analysis uses free energy calculations to examine variation in energy available to Fe(III) and SO42– reducers and methanogens because of changes in the bulk composition of brine and shallow groundwater following subsurface CO2 injection. Calculations were performed using data from two field experiments, the Frio Formation experiment and an experiment at the Zero Emission Research and Technology test site. Energy available for Fe(III) reduction increased significantly during CO2 injection in both experiments, largely because of a decrease in pH from near-neutral levels to just below 6. Energy available to SO42– reducers and methanogens varied little. These changes can lead to a greater rate of microbial Fe(III) reduction following subsurface CO2 injection in reservoirs where Fe(III) oxides or oxyhydroxides are available and the rate of Fe(III) reduction is limited by energy available prior to injection." @default.
• W2334631784 created "2016-06-24" @default.
• W2334631784 creator A5000614503 @default.
• W2334631784 date "2011-07-14" @default.
• W2334631784 modified "2023-09-25" @default.
• W2334631784 title "Variation in Energy Available to Populations of Subsurface Anaerobes in Response to Geological Carbon Storage" @default.
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• W2334631784 doi "https://doi.org/10.1021/es201279e" @default.
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• W2334631784 hasPublicationYear "2011" @default.
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