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• W2334656961 endingPage "1111" @default.
• W2334656961 startingPage "1106" @default.
• W2334656961 abstract "The synthesis of a series of digold hydroxide complexes is reported. These diaurated species, of the formula [{Au(NHC)}2(μ-OH)][BF4] (where NHC = IPrCl, IPr*, IPent), were easily prepared via the cationic species [Au(NHC)(NCCH3)][BF4] in aqueous media. The catalytic activity of these novel complexes was tested and compared to that of the previously reported IPr and SIPr derivatives. These digold hydroxide species are highly active in water-inclusive organic transformations, such as the alkyne and nitrile hydration reactions, and the Meyer–Schuster rearrangement. One salient feature of these systems is the lack of any additive to induce catalytic activity." @default.
• W2334656961 created "2016-06-24" @default.
• W2334656961 creator A5015962330 @default.
• W2334656961 creator A5035243107 @default.
• W2334656961 creator A5060095091 @default.
• W2334656961 creator A5078246445 @default.
• W2334656961 date "2013-02-06" @default.
• W2334656961 modified "2023-09-30" @default.
• W2334656961 title "[{Au(NHC)}₂(μ-OH)][BF₄]: <i>Silver-Free</i> and <i>Acid-Free</i> Catalysts for Water-Inclusive Gold-Mediated Organic Transformations" @default.
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• W2334656961 doi "https://doi.org/10.1021/om301249r" @default.
• W2334656961 hasPublicationYear "2013" @default.
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