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• W2334774005 endingPage "716" @default.
• W2334774005 startingPage "703" @default.
• W2334774005 abstract "Abstract In order to improve the optical properties and enhance the stability of Zn 1– x Cd x S nanoparticles, which are important optoelectrical materials, the ternary Zn 1– x Cd x S nanoparticles were enclosed in a layered octosilicate by a three-step process, namely (i) protonation of Naoctosilicate, (ii) ion-exchange in order to introduce Zn and Cd ions into the interlayer space, and (iii) addition of S 2– to form Zn 1– x Cd x S particles in the interlayer space of the octosilicate. The basal spacing (~10 Å) of the final ZnCdS-Oct-n (n = 1, 2, 3, 4) composites noticeably increased in comparison with that of the precursor H-Oct (7.5 Å). This may be attributed to the incorporation of larger size Zn 1– x Cd x S particles into the interlayer space of H-Oct. The UV-visible spectra of the composites suggested that the transmission band-edges gradually shifted to low energy with increasing molar ratio of Cd/Zn. Moreover, the transmission band-edges of the composites are between those of layered Octosilicate, ZnS, and CdS. TEM observation confirmed that the size of Zn 1– x Cd x S nanoparticles enclosed in the layered silicate was about ~3–5 nm." @default.
• W2334774005 created "2016-06-24" @default.
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• W2334774005 date "2014-12-01" @default.
• W2334774005 modified "2023-09-26" @default.
• W2334774005 title "Synthesis and optical properties of composites based on ternary Zn_1–<i>x</i>Cd_<i>x</i>S nanoparticles enclosed in a layered octosilicate" @default.
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• W2334774005 doi "https://doi.org/10.1180/claymin.2014.049.5.07" @default.
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