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• W2334798071 abstract "Controlled/living radical polymerization techniques have transformed polymer chemistry in the last few decades, affording the production of polymers with precise control over both molecular weights and architectures. It is now possible to synthesize almost an infinite variety of macromolecules using nonspecialized equipment, finding applications in high-tech industry. However, they have several shortcomings. Until recently, living radical polymerizations could not be controlled by an external stimulus, such as visible light, pH, mechanical, chemical, etc. Moreover, they are usually sensitive to trace amounts of oxygen in the system. In this Article, we report a photoinduced living polymerization technique, which is able to polymerize a large range of monomers, including conjugated and unconjugated monomers, using ultralow concentrations of an iridium-based photoredox catalyst (typically 1 ppm to monomers) and a low energy visible LED as the light source (1-4.8 W, λ(max) = 435 nm). The synthesis of homopolymers with molecular weights ranging from 1000 to 2,000,000 g/mol was successfully achieved with narrow molecular weight distributions (M(w)/M(n) < 1.3). In addition, chain extensions of poly(methacrylate)s, poly(styrene), poly(N-vinyl pyrrolidinone), poly(vinyl ester)s, and poly(acrylate)s were performed to prepare diblock copolymers. The reusability of the catalyst was demonstrated by the synthesis of a decablock polymer by multiple chain extensions. Most importantly, this process was employed to prepare well-defined polymers and multiblock copolymers in the presence of air." @default.
• W2334798071 created "2016-06-24" @default.
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• W2334798071 creator A5034272377 @default.
• W2334798071 creator A5041465537 @default.
• W2334798071 creator A5041558999 @default.
• W2334798071 date "2014-04-01" @default.
• W2334798071 modified "2023-10-10" @default.
• W2334798071 title "A Robust and Versatile Photoinduced Living Polymerization of Conjugated and Unconjugated Monomers and Its Oxygen Tolerance" @default.
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• W2334798071 cites W1969719690 @default.
• W2334798071 cites W1973609141 @default.
• W2334798071 cites W1974895711 @default.
• W2334798071 cites W1980349462 @default.
• W2334798071 cites W1980754233 @default.
• W2334798071 cites W1981545796 @default.
• W2334798071 cites W1982915834 @default.
• W2334798071 cites W1983224931 @default.
• W2334798071 cites W1985218999 @default.
• W2334798071 cites W1996941025 @default.
• W2334798071 cites W2002007707 @default.
• W2334798071 cites W2008205734 @default.
• W2334798071 cites W2008512441 @default.
• W2334798071 cites W2010018976 @default.
• W2334798071 cites W2019140159 @default.
• W2334798071 cites W2019583836 @default.
• W2334798071 cites W2023710734 @default.
• W2334798071 cites W2023807352 @default.
• W2334798071 cites W2026134775 @default.
• W2334798071 cites W2028227189 @default.
• W2334798071 cites W2040133892 @default.
• W2334798071 cites W2040338441 @default.
• W2334798071 cites W2043924688 @default.
• W2334798071 cites W2046277144 @default.
• W2334798071 cites W2046598293 @default.
• W2334798071 cites W2049053508 @default.
• W2334798071 cites W2050379798 @default.
• W2334798071 cites W2051712827 @default.
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• W2334798071 cites W2075972713 @default.
• W2334798071 cites W2077479948 @default.
• W2334798071 cites W2079011492 @default.
• W2334798071 cites W2083141150 @default.
• W2334798071 cites W2087016766 @default.
• W2334798071 cites W2090568310 @default.
• W2334798071 cites W2093527245 @default.
• W2334798071 cites W2094125851 @default.
• W2334798071 cites W2096405682 @default.
• W2334798071 cites W2106473549 @default.
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• W2334798071 cites W2162225842 @default.
• W2334798071 cites W2164036856 @default.
• W2334798071 cites W2167539127 @default.
• W2334798071 cites W2167820411 @default.
• W2334798071 cites W2170981512 @default.
• W2334798071 cites W2171847332 @default.
• W2334798071 cites W2316585167 @default.
• W2334798071 cites W2317563595 @default.
• W2334798071 cites W2318492860 @default.
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• W2334798071 cites W2321217143 @default.
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• W2334798071 doi "https://doi.org/10.1021/ja501745g" @default.
• W2334798071 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24689993" @default.
• W2334798071 hasPublicationYear "2014" @default.
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