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- W2334802477 abstract "ABSTRACT Poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) has been studied for a wide range of applications due to its potential as a transparent electrode. Herein, the use of imidazole and its derivatives as a neutralizing additive for PEDOT:PSS dispersion and in‐depth studies of their effects in terms of electrical properties and stability is reported. Although the neutralization in general reduces the electrical conductivity of PEDOT:PSS, the conductivity after imidazole treatment (685.2 S cm −1 ) is higher than that after treatment of other derivatives. Spectroscopic and thermoelectric studies show that the de‐doping effect resulted in the conductivity reduction. As a trade‐off of the conductivity reduction, greatly enhanced long‐term stability and noncorrosive characteristics are obtained after neutralization. The change in sheet resistance of imidazole‐treated PEDOT:PSS after 500 h under harsh conditions (85 °C and 85% humidity) is half that of the untreated samples, demonstrating the great enhancement of the stability. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54 , 1530–1536" @default.
- W2334802477 created "2016-06-24" @default.
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- W2334802477 date "2016-04-05" @default.
- W2334802477 modified "2023-09-25" @default.
- W2334802477 title "Influence of imidazole‐based acidity control of <scp>PEDOT:PSS</scp> on its electrical properties and environmental stability" @default.
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- W2334802477 doi "https://doi.org/10.1002/polb.24048" @default.
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