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- W2334806005 abstract "The cytoplasmic water-soluble p-glucans of Achlya bisexualis are (1?>3)-linked polysaccharides of two types: a small neutral and a large phosphorylat- ed. The carbon-13 nuclear magnetic resonance (NMR) spectrum of neutral glucan is consistent with a (l-^3)-(3-glucan with some (1?>6)-(3-linkages. Meth- ylation analysis suggests a similar structure, but also shows about 6% each of other linkages and other sugars. Acid and enzyme hydrolysis data also support a moderately branched (1??3)-p-glucan probably with single (1?>6)-p-glucopyranosyl segments. The data, however, do not exclude the possibility that the branches are extended (1?>3)-linked residues. The molecular mass of neutral glucan is approximately 9000 with a dp of 50, when compared with algal 1am- inaran by gel filtration chromatography. The carbon- 13 NMR spectrum of phosphoglucan is qualitatively similar to that of neutral glucan. Aqueous hydrofluor- ic acid effectively cleaves phosphate from the phos? phoglucan and produces a polymer of the size of neutral glucan. This material is both qualitatively and quantitatively identical to neutral glucan in its car? bon-13 NMR spectrum. The phosphorus-31 NMR spectrum of the phosphoglucan reveals both mono- and diphosphoester linkages. We propose that the phosphodiester covalent bonds convert the smaller polymer into the very large phosphoglucan." @default.
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- W2334806005 date "1996-03-01" @default.
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- W2334806005 title "Water-soluble reserve polysaccharides from Achlya are (1→3)-β-glucans" @default.
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- W2334806005 doi "https://doi.org/10.1080/00275514.1996.12026652" @default.
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