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- W2334812133 abstract "The binding of small gas molecules to metalloporphyrins is of both fundamental scientific and technological interest. It plays a key role in the transport of respiratory gases, catalytic processes in biological systems, and artificial nanostructures for sensing. Here, we present a detailed molecular-level investigation regarding the interaction of nitrogen monoxide (NO) and carbon monoxide (CO) with metallo-tetraphenylporphyrin (M−TPP, M = Co, Fe) arrays, anchored on a noble metal Ag(111) surface, providing M−TPP species with a distinct saddle-shape conformation. Scanning tunneling microscopy and spectroscopy experiments reveal that the impact of CO and NO is strikingly different on both species. In the case of CO, the M−TPP core can be dressed by either one or two carbon monoxide ligands, whereby the porphyrin geometric and electronic structure remains nearly unaffected. In contrast, following NO exposure exclusively a mononitrosyl species evolves. The NO axial ligation induces a relaxation of the adsorption-induced molecular deformation and markedly modifies the electronic structure of the porphyrin." @default.
- W2334812133 created "2016-06-24" @default.
- W2334812133 creator A5007444128 @default.
- W2334812133 creator A5081095037 @default.
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- W2334812133 date "2010-12-02" @default.
- W2334812133 modified "2023-09-30" @default.
- W2334812133 title "Discriminative Response of Surface-Confined Metalloporphyrin Molecules to Carbon and Nitrogen Monoxide" @default.
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- W2334812133 doi "https://doi.org/10.1021/ja1054884" @default.
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