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- W2334851676 abstract "The electrical double layer is examined using a generalized Poisson-Boltzmann equation that takes into account the finite ion size by modeling the aqueous electrolyte solution as a suspension of polarizable insulating spheres in water. We find that this model greatly amplifies the steric effects predicted by the usual modified Poisson-Boltzmann equation, which imposes only a restriction on the ability of ions to approach one another. This amplification should allow for an interpretation of the experimental results using reasonable effective ionic radii (close to their well-known hydrated values)." @default.
- W2334851676 created "2016-06-24" @default.
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- W2334851676 date "2011-11-03" @default.
- W2334851676 modified "2023-10-07" @default.
- W2334851676 title "Poisson–Boltzmann Description of the Electrical Double Layer Including Ion Size Effects" @default.
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- W2334851676 doi "https://doi.org/10.1021/la2025445" @default.
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