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- W2334854796 abstract "The aromatizing ring-closing metathesis has been shown to take place inside an extended porous framework. Employing a combination of solvent-assisted linker exchange and postsynthesis modification using olefin metathesis, the noninterpenetrated SALEM-14 was formed and converted catalytically into PAH-MOF-1 with polycyclic aromatic hydrocarbon (PAH) pillars. The metal–organic framework in SALEM-14 prevents “intermolecular” olefin metathesis from occurring between the pillars in the presence of the first generation Hoveyda–Grubbs catalyst, while favoring the production of a PAH, which can be released from the framework under acidic conditions in dimethylsulfoxide." @default.
- W2334854796 created "2016-06-24" @default.
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- W2334854796 date "2013-09-26" @default.
- W2334854796 modified "2023-09-25" @default.
- W2334854796 title "Aromatizing Olefin Metathesis by Ligand Isolation inside a Metal– Organic Framework" @default.
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- W2334854796 doi "https://doi.org/10.1021/ja407333q" @default.
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