FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2334861405> ?p ?o ?g. }

• W2334861405 endingPage "3535" @default.
• W2334861405 startingPage "3523" @default.
• W2334861405 abstract "The discovery of a diiron organometallic site in nature within the diiron hydrogenase, [FeFe]-H2ase, active site has prompted revisits of the classic organometallic chemistry involving the Fe–Fe bond and bridging ligands, particularly of the (μ-SCH2XCH2S)[Fe(CO)3]2 and (μ-SCH2XCH2S)[Fe(CO)2L]2 (X = CH2, NH; L = PMe3, CN–, and NHC’s (NHC = N-heterocyclic carbene)), derived from CO/L exchange reactions. Through the synergy of synthetic chemistry and density functional theory computations, the regioselectivity of nucleophilic (PMe3 or CN–) and electrophilic (nitrosonium, NO+) ligand substitution on the diiron dithiolate framework of the (μ-pdt)[Fe(CO)2NHC][Fe(CO)3] complex (pdt = propanedithiolate) reveals the electron density shifts in the diiron core of such complexes that mimic the [FeFe]-H2ase active site. While CO substitution by PMe3, followed by reaction with NO+, produces (μ-pdt)(μ-CO)[Fe(NHC)(NO)][Fe(CO)2PMe3]+, the alternate order of reagent addition produces the structural isomer (μ-pdt)[Fe(NHC)(NO)PMe3][Fe(CO)3]+, illustrating how the nucleophile and electrophile choose the electron-poor metal and the electron-rich metal, respectively. Theoretical explorations of simpler analogues, (μ-pdt)[Fe(CO)2CN][Fe(CO)3]−, (μ-pdt)[Fe(CO)3]2, and (μ-pdt)[Fe(CO)2NO][Fe(CO)3]+, provide an explanation for the role that the electron-rich iron moiety plays in inducing the rotation of the electron-poor iron moiety to produce a bridging CO ligand, a key factor in stabilizing the electron-rich iron moiety and for support of the rotated structure as found in the enzyme active site." @default.
• W2334861405 created "2016-06-24" @default.
• W2334861405 creator A5001382710 @default.
• W2334861405 creator A5032201164 @default.
• W2334861405 creator A5051429869 @default.
• W2334861405 creator A5061126493 @default.
• W2334861405 creator A5065780097 @default.
• W2334861405 creator A5067415356 @default.
• W2334861405 date "2015-03-13" @default.
• W2334861405 modified "2023-09-24" @default.
• W2334861405 title "Regioselectivity in Ligand Substitution Reactions on Diiron Complexes Governed by Nucleophilic and Electrophilic Ligand Properties" @default.
• W2334861405 cites W1969520480 @default.
• W2334861405 cites W1971275758 @default.
• W2334861405 cites W1971396352 @default.
• W2334861405 cites W1975708211 @default.
• W2334861405 cites W1978160387 @default.
• W2334861405 cites W1980063369 @default.
• W2334861405 cites W1982792433 @default.
• W2334861405 cites W1983759499 @default.
• W2334861405 cites W1988841674 @default.
• W2334861405 cites W1994229205 @default.
• W2334861405 cites W2004658142 @default.
• W2334861405 cites W2012073519 @default.
• W2334861405 cites W2013044080 @default.
• W2334861405 cites W2021444944 @default.
• W2334861405 cites W2022113368 @default.
• W2334861405 cites W2023271753 @default.
• W2334861405 cites W2024564951 @default.
• W2334861405 cites W2030484939 @default.
• W2334861405 cites W2032552102 @default.
• W2334861405 cites W2041298522 @default.
• W2334861405 cites W2042663882 @default.
• W2334861405 cites W2043529795 @default.
• W2334861405 cites W2046545090 @default.
• W2334861405 cites W2051748008 @default.
• W2334861405 cites W2055281567 @default.
• W2334861405 cites W2059505744 @default.
• W2334861405 cites W2059628993 @default.
• W2334861405 cites W2060801760 @default.
• W2334861405 cites W2062417798 @default.
• W2334861405 cites W2063074480 @default.
• W2334861405 cites W2063334178 @default.
• W2334861405 cites W2067685130 @default.
• W2334861405 cites W2070887425 @default.
• W2334861405 cites W2071245797 @default.
• W2334861405 cites W2072348323 @default.
• W2334861405 cites W2077753877 @default.
• W2334861405 cites W2082334266 @default.
• W2334861405 cites W2086945873 @default.
• W2334861405 cites W2091258026 @default.
• W2334861405 cites W2092788243 @default.
• W2334861405 cites W2105249240 @default.
• W2334861405 cites W2136665241 @default.
• W2334861405 cites W2139486238 @default.
• W2334861405 cites W2143981217 @default.
• W2334861405 cites W2148284063 @default.
• W2334861405 cites W2318712667 @default.
• W2334861405 cites W2401217930 @default.
• W2334861405 cites W2556880991 @default.
• W2334861405 cites W2950345845 @default.
• W2334861405 cites W4211159207 @default.
• W2334861405 doi "https://doi.org/10.1021/acs.inorgchem.5b00072" @default.
• W2334861405 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25767959" @default.
• W2334861405 hasPublicationYear "2015" @default.
• W2334861405 type Work @default.
• W2334861405 sameAs 2334861405 @default.
• W2334861405 citedByCount "12" @default.
• W2334861405 countsByYear W23348614052015 @default.
• W2334861405 countsByYear W23348614052016 @default.
• W2334861405 countsByYear W23348614052017 @default.
• W2334861405 countsByYear W23348614052020 @default.
• W2334861405 countsByYear W23348614052021 @default.
• W2334861405 countsByYear W23348614052023 @default.
• W2334861405 crossrefType "journal-article" @default.
• W2334861405 hasAuthorship W2334861405A5001382710 @default.
• W2334861405 hasAuthorship W2334861405A5032201164 @default.
• W2334861405 hasAuthorship W2334861405A5051429869 @default.
• W2334861405 hasAuthorship W2334861405A5061126493 @default.
• W2334861405 hasAuthorship W2334861405A5065780097 @default.
• W2334861405 hasAuthorship W2334861405A5067415356 @default.
• W2334861405 hasConcept C111185830 @default.
• W2334861405 hasConcept C116569031 @default.
• W2334861405 hasConcept C155647269 @default.
• W2334861405 hasConcept C161790260 @default.
• W2334861405 hasConcept C170493617 @default.
• W2334861405 hasConcept C178790620 @default.
• W2334861405 hasConcept C178907741 @default.
• W2334861405 hasConcept C185592680 @default.
• W2334861405 hasConcept C2776568683 @default.
• W2334861405 hasConcept C2777164566 @default.
• W2334861405 hasConcept C50027330 @default.
• W2334861405 hasConcept C55493867 @default.
• W2334861405 hasConcept C59759590 @default.
• W2334861405 hasConcept C71240020 @default.
• W2334861405 hasConceptScore W2334861405C111185830 @default.
• W2334861405 hasConceptScore W2334861405C116569031 @default.
• W2334861405 hasConceptScore W2334861405C155647269 @default.
• W2334861405 hasConceptScore W2334861405C161790260 @default.

• next