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• W2334888928 endingPage "7092" @default.
• W2334888928 startingPage "7085" @default.
• W2334888928 abstract "Reactions of both terminal and internal alkynols with ReOCl2(OEt)(PPh3)2 (1) are described. Treatment of ReOCl2(OEt)(PPh3)2 (1) with HC≡CC6H4-2-CH2OH and HC≡CCH2CH2CH2OH produced the six-membered ylide complexes ReOCl2(C(═CH(PPh3))-C6H4-CH2O)(PPh3) (2) and ReOCl2(C(═CH(PPh3))CH2CH2CH2O)(PPh3) (3), respectvely, derived from addition of PPh3 to the terminal alkyne carbon. Similarly, phosphine addition to the terminal alkyne carbon occurred in the reactions of ReOCl2(OEt)(PPh3)2 (1) with HC≡CCH2CH(OH)Me and HC≡CCH2CH(OH)CH(OH)CH2C≡CH to give the five-membered ylide complexes ReOCl2(C(═CH(PPh3))CH2CH2CHMeO)(PPh3) (5) and {ReOCl2(C(═CH(PPh3)CH2CHO)(PPh3)}2 (6), respectively. Interestingly, related reactions of ReOCl2(OEt)(PPh3)2 with RC≡CCH2CH2OH (R = Me, Et, Ph) produced the six-membered ylide complexes ReOCl2(CR═C(PPh3)CH2CH2O)(PPh3) (7, R = Me; 8, R = Et; 9, R = Ph), derived from addition of PPh3 to the alkyne carbon closer to the OH group." @default.
• W2334888928 created "2016-06-24" @default.
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• W2334888928 date "2012-10-02" @default.
• W2334888928 modified "2023-10-16" @default.
• W2334888928 title "Synthesis of Alkenyl Ylide Complexes from Reactions of ReOCl₂(OEt)(PPh₃)₂ with Alkynols" @default.
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• W2334888928 doi "https://doi.org/10.1021/om3005788" @default.
• W2334888928 hasPublicationYear "2012" @default.
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