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• W2334892888 endingPage "7060" @default.
• W2334892888 startingPage "7052" @default.
• W2334892888 abstract "Rapid, efficient methods have been developed to prepare phenols from the oxidation of arylhydrosilanes. The effects of arene substituents and fluoride promoters on this process show that while electron-deficient arenes can undergo direct oxidation from the hydrosilane, electron-rich aromatics benefit from silane activation via oxidation to the methoxysilane using homogeneous or heterogeneous transition metal catalysis. The combination of these two oxidations into a streamlined flow procedure involving minimal processing of reaction intermediates is also reported." @default.
• W2334892888 created "2016-06-24" @default.
• W2334892888 creator A5033987976 @default.
• W2334892888 creator A5056328702 @default.
• W2334892888 creator A5088141048 @default.
• W2334892888 date "2012-08-06" @default.
• W2334892888 modified "2023-10-18" @default.
• W2334892888 title "Synthesis of Phenols via Fluoride-free Oxidation of Arylsilanes and Arylmethoxysilanes" @default.
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• W2334892888 doi "https://doi.org/10.1021/jo301363h" @default.
• W2334892888 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22866602" @default.
• W2334892888 hasPublicationYear "2012" @default.
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