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- W2334983934 abstract "Mixtures of Zr(SO4)2-Zr(OH)4-H2O system were hydrothermally treated at temperatures from 160 to 240°C for various time periods. A metastable compound, pseudo-zirconium oxide sulfate (PZOS), was formed at the early stage of the hydrothermal process. In solutions containing 0.4mol/l of H2SO4, an isotropic, elongated, flaky m-ZrO2 particles were formed subsequently, and the particle size increased with increase in treatment time. The m-ZrO2 particles crystallized from the PZOS by discharging SO42- ions. In solutions containing 1.0 or 1.5mol/l of H2SO4, however, the subsequent product was zirconium oxide sulfate (ZOS) particles, which probably resulted by the nucleation and crystal growth mechanism. The yield of ZOS particles or elongated, flaky m-ZrO2 particles from Zr(SO4)2-Zr(OH)4-H2O system was higher than that from Zr(SO4)2-H2O system. This method in this study is expected to be useful in the mass volume production of ZOS or m-ZrO2 particles." @default.
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- W2334983934 date "1994-01-01" @default.
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- W2334983934 title "Products of Thermal Hydrolysis in Zr(SO<sub>4</sub>)<sub>2</sub>-Zr(OH)<sub>4</sub>-H<sub>2</sub>O System" @default.
- W2334983934 doi "https://doi.org/10.2109/jcersj.102.844" @default.
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