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- W2335073072 abstract "Multiblock copolymers consisting of crystalline poly(butylene succinate) and amorphous poly(1,2-propylene succinate) (PBS-co-PPS) are synthesized. The microstructure of the materials is investigated by the combination of thermal analysis and wide-angle/small-angle X-ray scattering (WAXS/SAXS). The noncrystalline PPS blocks are found to locate predominately in the amorphous phase between crystalline lamellae of PBS. By means of in situ WAXS coupled with optical-assisted strain measurement, the deformation process of PBS-co-PPS is studied. The stiffness and strength of PBS-co-PPS decrease with increasing PPS fraction, while the strain recovery behavior of PBS-co-PPS is similar to PBS homopolymer. Transition from α crystal to β crystal is observed for all the PBS-co-PPS samples. The critical stress for α–β transition of PBS-co-PPS is determined, which is found to be independent of PPS blocks. The universal critical stress for crystal transition is interpreted through a single-microfibril-stretching mechanism." @default.
- W2335073072 created "2016-06-24" @default.
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- W2335073072 date "2014-10-23" @default.
- W2335073072 modified "2023-10-11" @default.
- W2335073072 title "Critical Stress for Crystal Transition in Poly(butylene succinate)-Based Crystalline–Amorphous Multiblock Copolymers" @default.
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- W2335073072 doi "https://doi.org/10.1021/ma501832z" @default.
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