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- W2335117890 abstract "A hollow-cathode glow discharge device for element-selective gas chromatography detection is evaluated. The device is used with a vacuum-outlet GC for the plasma emission detection of some nonmetallic elements. The GC column passes directly into the hollow cathode cavity. The cavity volume is about 10 μL. The device is operated in a pressure range of about 10 to 100 Torr with plasma currents from 15 to 150 mA. Polymer formation occurs in the cathode cavity during passage of large quantities of solvent. Strategies for controlling these processes are discussed. When used for high speed GC detection, some tailing is observed, particularly for fluorinated compounds. The effects of electrode geometry, plasma current, and plasma pressure on relative emission intensities and detector band shapes are described for the element selective detection of F-containing compounds." @default.
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- W2335117890 date "1992-04-01" @default.
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- W2335117890 title "Characterization of a Low-Pressure Microvolume Plasma Emission Detector for Gas Chromatography" @default.
- W2335117890 doi "https://doi.org/10.1093/chromsci/30.4.136" @default.
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