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- W2335220877 abstract "This study is a continuation of our previous works on the use of metal-based nanoparticles for the adsorption of asphaltenes and its subsequent catalytic thermal decomposition. In this study, we evaluated the effects of asphaltene aggregation on the adsorption process and the subsequent catalytic oxidation using fumed silica and nanoparticles of NiO and/or PdO supported on fumed silica. Adsorption isotherms were constructed through batch adsorption experiments at 25 °C by using mixtures of n-heptane and toluene in amounts of 0, 20% v/v n-heptane (Heptol 20), and 40% v/v n-heptane (Heptol 40) to obtain different aggregate sizes of asphaltenes. Subsequently, asphaltene oxidation in the presence and absence of the nanoparticles was carried out in a TGA/FTIR system to investigate the impact of adsorbed asphaltene aggregates on the catalytic activity of the selected nanoparticles. The adsorption isotherms were described by the solid–liquid equilibrium (SLE) model, and the catalytic behavior of the nanoparticle..." @default.
- W2335220877 created "2016-06-24" @default.
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- W2335220877 date "2015-02-27" @default.
- W2335220877 modified "2023-10-13" @default.
- W2335220877 title "Influence of Asphaltene Aggregation on the Adsorption and Catalytic Behavior of Nanoparticles" @default.
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- W2335220877 doi "https://doi.org/10.1021/ef502786e" @default.
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