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- W2335235529 abstract "Spectrophotometric titrations were conducted on the system horse heart ferricytochrome c plus ferrohexacyanide in the pH range 5 to 7 and at temperatures 8, 18, 22 and 28°C. A difference extinction coefficient for reduced vs. oxidized cy- tochrome c at 550 nm of 21 mmol-lcm -I was used in part of the evaluations. On the assumption that only one electron-transfer- linked proton dissociation is effective for both ferro- and ferricytochrome c in this pH range, various possible models are developed with only three conforming with the experimental pH dependence of the spectrophotometric equilibrium constant. The data conform best to a model with protonic dissociation constants between pH 5 and 7 such that the reduced cytochrome c species is at least a factor of 3 more acidic than the one for WP" @default.
- W2335235529 created "2016-06-24" @default.
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- W2335235529 date "1981-01-01" @default.
- W2335235529 modified "2023-09-26" @default.
- W2335235529 title "WITH FERROHEXACYANIDE IN THE pH RANGE 5 TO 7" @default.
- W2335235529 hasPublicationYear "1981" @default.
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