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- W2335269355 abstract "We report resonance-enhanced two-photon ionization photo-electron spectroscopy of jet-cooled benzene via the 6(1)1(n) (n = 0-3) vibronic levels in S(1)((1)B(2u) π,π*) using a nanosecond UV laser and photoelectron imaging. The best energy resolution (ΔE/E) was 0.7%. The photoelectron spectrum from the S(1) 6(1)1(3) level (E(vib) = 3284 cm(-1)) in the channel three region exhibited a clear signature of intramolecular vibrational redistribution (IVR). The spectral features were consistent with picosecond zero kinetic energy photoelectron (ZEKE) spectra reported by Smith et al. [ J. Phys. Chem. 1995, 99, 1768]. The photoelectron angular anisotropy parameter β(2) was found to be negative in ionization from the 6(1)1(n) (n = 0-3) levels with photoelectron kinetic energies up to 5000 cm(-1). No influence of a shape resonance was identified." @default.
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- W2335269355 date "2011-03-02" @default.
- W2335269355 modified "2023-09-26" @default.
- W2335269355 title "Photoelectron Imaging Spectroscopy of S1(1B2u π,π*) Benzene via 611n (n = 0−3) Levels" @default.
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- W2335269355 doi "https://doi.org/10.1021/jp110557n" @default.
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