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• W2335528454 abstract "Low density silica xerogels were obtained by reducing the capillary forces and thus the shrinkage upon ambient pressure drying. This was achieved by increasing the particle and thus also the pore size at a given target density. To increase the particle size beyond the values characteristic for classical silica aerogels, particle growth and formation of the interconnected network were decoupled. Uniform silica nanoparticles of 20 to 30 nm in diameter synthesized by a Stober process were subsequently cross-linked. To strengthen the gel network additional treatments were applied including an organic coating of the gel structure. For that purpose 3-Aminopropyltriethoxysilane (APTES) was used as a linker between the inner surface of the silica backbone and the organic component. Simultaneously, APTES serves as a catalyst for the gelation. Since the components for the organic coating of the silica backbone do not interfere with the network formation, a one-pot synthesis is feasible. Several bifunctional epoxide..." @default.
• W2335528454 created "2016-06-24" @default.
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• W2335528454 date "2013-09-11" @default.
• W2335528454 modified "2023-10-04" @default.
• W2335528454 title "Cross-Linked Monolithic Xerogels Based on Silica Nanoparticles" @default.
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• W2335528454 doi "https://doi.org/10.1021/cm401717q" @default.
• W2335528454 hasPublicationYear "2013" @default.
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