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• W2335638962 abstract "The reactions of Au(tht)Cl (tht = tetrahydrothiophene) with the electron-rich-arene-spacer-containing polyphosphine ligands N,N′-bis((diphenylphosphino)methyl)benzene-1,4-diamine (Dpba), N,N′-bis((diphenylphosphino)methyl)naphthalene-1,5-diamine (Dpna), N,N,N′,N′- tetrakis((diphenylphosphino)methyl)benzene-1,4-diamine (Pbaa), N,N,N′,N′-tetrakis((diphenylphosphino)methyl)naphthalene-1,5-diamine (Pnaa), and N,N,N′,N′-tetrakis((diphenylphosphino)methyl)biphenyl-4,4′-diamine (Pbbaa) lead to [Dpba(AuCl)2] (1), [Dpna(AuCl)2] (2), [Pnaa(AuCl)4] (3), [Pbbaa(AuCl)4 (4). and [Pbaa(AuCl)4] (5), which are characterized by 1H and 31P NMR, IR, elemental analysis, and X-ray crystal structure analysis. These complexes exhibit weak Au–arene interactions with the electron-rich arene spacer, while the Au–arene interactions are modified by a combination of electronic and steric effects from the ligands. Different from monomeric complexes 1, 2, 3, and 4, complex 5 in the solid state exhibits a centrosymmetric trimeric unit that is constructed by intermolecular Au···Au interactions between the central molecule and the two symmetry-related terminal molecules and in which the conformation of the central molecule is different from that of the two symmetric terminal molecules. On the basis of the Kochi’s geometric criteria and the crystal structural parameters relating to Au–arene interactions, the Au···Carene contacts in 3 and 4 feature nearly η2-arene interactions, while the Au···Carene contacts in 5 can be described as η1-arene interactions, and the Au···Carene contacts in 1 and 2 are very weak due to intermolecular N–H···Cl interactions." @default.
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• W2335638962 date "2012-03-02" @default.
• W2335638962 modified "2023-09-27" @default.
• W2335638962 title "Gold(I) Chloride Complexes of Polyphosphine Ligands with Electron-Rich Arene Spacer: Gold–Arene Interactions" @default.
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• W2335638962 doi "https://doi.org/10.1021/om201276w" @default.
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