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- W2335670124 abstract "Cathode using the olivine particles was subjected to an open-circuit voltage measurement under the relaxation condition of 24 h at each SOC and DOD states. The electrochemical reaction in the LiFePO4 cathode was composed of a large plateau around 3.45 V with sloped regions nearby for both the fully charged and discharged states. It was found that the potential profile in the sloped regions exhibited a hysteresis. Furthermore, both sloped regions became narrower when the operating temperature was raised from 30 to 60°C. Furthermore, it was found that the apparent diffusion coefficient of Li+ ions in the sloped regions was much smaller than that in the plateau region. These facts implied that the obtained profiles were not in an equilibrium state with a quasi-OCV profile than the real one, and that the potential relaxation in the sloped regions took an extremely long time." @default.
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- W2335670124 date "2010-01-01" @default.
- W2335670124 modified "2023-09-25" @default.
- W2335670124 title "Open Circuit Voltage of LixFePO4 Olivine Cathode and Its Electrochemical Reaction" @default.
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- W2335670124 doi "https://doi.org/10.2497/jjspm.57.725" @default.
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