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- W2335758618 endingPage "3698" @default.
- W2335758618 startingPage "3687" @default.
- W2335758618 abstract "The synthesis of four novel heteroleptic dipyrrinato complexes [(η(6)-arene)RuCl(2-pcdpm)] (η(6)-arene = C6H6, 1; C10H14, 2) and [(η(5)-C5Me5)MCl(2-pcdpm)] (M = Rh, 3; Ir, 4) containing a new chelating ligand 4-(2-methoxypyridyl)-phenyldipyrromethene (2-pcdpm) have been described. The complexes 1-4 have been fully characterized by various physicochemical techniques, namely, elemental analyses, spectral (ESI-MS, IR, (1)H, (13)C NMR, UV/vis) and electrochemical studies (cyclic voltammetry (CV) and differential pulse voltammetry (DPV)). Structures of 3 and 4 have been determined crystallographically. In vitro antiproliferative and cytotoxic activity of these complexes has been evaluated by trypan blue exclusion assay, cell morphology, apoptosis, acridine orange/ethidium bromide (AO/EtBr) fluorescence staining, and DNA fragmentation assay in Dalton lymphoma (DL) cell lines. Interaction of 1-4 with calf thymus DNA (CT DNA) has also been supported by absorption titration and electrochemical studies. Our results suggest that in vitro antitumor activity of 1-4 lies in the order 2 > 1 > 4 > 3." @default.
- W2335758618 created "2016-06-24" @default.
- W2335758618 creator A5017336902 @default.
- W2335758618 creator A5026944098 @default.
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- W2335758618 creator A5034434638 @default.
- W2335758618 creator A5043450815 @default.
- W2335758618 creator A5054304542 @default.
- W2335758618 creator A5056554030 @default.
- W2335758618 creator A5064109029 @default.
- W2335758618 creator A5089296810 @default.
- W2335758618 date "2013-03-11" @default.
- W2335758618 modified "2023-10-03" @default.
- W2335758618 title "DNA Binding and Anti-Cancer Activity of Redox-Active Heteroleptic Piano-Stool Ru(II), Rh(III), and Ir(III) Complexes Containing 4-(2-Methoxypyridyl)phenyldipyrromethene" @default.
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