Matches in SemOpenAlex for { <https://semopenalex.org/work/W2335992079> ?p ?o ?g. }
- W2335992079 endingPage "886" @default.
- W2335992079 startingPage "877" @default.
- W2335992079 abstract "The complexation of uranium and europium, in oxidation states +VI and +III, respectively, was investigated with pertinent bio-inorganic systems. Three aspartate-rich pentapeptides with different structural properties were selected for study to rationalize the structure–affinity relationships. Thermodynamic results, crosschecked by both isothermal titration calorimetry and time-resolved laser fluorescence spectroscopy, showed different affinity depending on the peptide for both Eu(III) and U(VI). The thermodynamic aspects were correlated to structural predictions, which were acquired by density functional theory quantum chemical calculations and from IR and extended X-ray absorption fine structure experiments. The combination of these microscopic properties revealed that carbonyl–metal interactions affected the entropy in the case of europium, while the larger uranyl cation was mostly affected by preorganization and steric effects, so that the affinity was enhanced through enthalpy. The approach described here revealed various microscopic aspects governing peptide actinide affinity. Highlighting these mechanisms should certainly contribute to the rational synthesis of higher affinity biomimetic aspartic ligands." @default.
- W2335992079 created "2016-06-24" @default.
- W2335992079 creator A5001278291 @default.
- W2335992079 creator A5009043932 @default.
- W2335992079 creator A5049932254 @default.
- W2335992079 creator A5057589578 @default.
- W2335992079 creator A5059418406 @default.
- W2335992079 creator A5067359625 @default.
- W2335992079 creator A5074089741 @default.
- W2335992079 creator A5079213443 @default.
- W2335992079 creator A5084740308 @default.
- W2335992079 date "2016-01-04" @default.
- W2335992079 modified "2023-09-26" @default.
- W2335992079 title "Thermodynamic and Structural Investigation of Synthetic Actinide–Peptide Scaffolds" @default.
- W2335992079 cites W1965543693 @default.
- W2335992079 cites W1974494035 @default.
- W2335992079 cites W1975211366 @default.
- W2335992079 cites W1983138570 @default.
- W2335992079 cites W1989292165 @default.
- W2335992079 cites W1996381176 @default.
- W2335992079 cites W1998718581 @default.
- W2335992079 cites W2011652269 @default.
- W2335992079 cites W2013564334 @default.
- W2335992079 cites W2015697056 @default.
- W2335992079 cites W2025218147 @default.
- W2335992079 cites W2027435994 @default.
- W2335992079 cites W2044959599 @default.
- W2335992079 cites W2046855772 @default.
- W2335992079 cites W2054040797 @default.
- W2335992079 cites W2060349265 @default.
- W2335992079 cites W2065398277 @default.
- W2335992079 cites W2070227796 @default.
- W2335992079 cites W2070458959 @default.
- W2335992079 cites W2071448244 @default.
- W2335992079 cites W2077158294 @default.
- W2335992079 cites W2085598274 @default.
- W2335992079 cites W2087705205 @default.
- W2335992079 cites W2090495747 @default.
- W2335992079 cites W2092160810 @default.
- W2335992079 cites W2094855897 @default.
- W2335992079 cites W2097422001 @default.
- W2335992079 cites W2102182028 @default.
- W2335992079 cites W2102705131 @default.
- W2335992079 cites W2104367814 @default.
- W2335992079 cites W2139796663 @default.
- W2335992079 cites W2143981217 @default.
- W2335992079 cites W2155102432 @default.
- W2335992079 cites W2160174308 @default.
- W2335992079 cites W2322430121 @default.
- W2335992079 cites W2335015386 @default.
- W2335992079 cites W2570342360 @default.
- W2335992079 doi "https://doi.org/10.1021/acs.inorgchem.5b02379" @default.
- W2335992079 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26727631" @default.
- W2335992079 hasPublicationYear "2016" @default.
- W2335992079 type Work @default.
- W2335992079 sameAs 2335992079 @default.
- W2335992079 citedByCount "9" @default.
- W2335992079 countsByYear W23359920792016 @default.
- W2335992079 countsByYear W23359920792017 @default.
- W2335992079 countsByYear W23359920792018 @default.
- W2335992079 countsByYear W23359920792019 @default.
- W2335992079 countsByYear W23359920792020 @default.
- W2335992079 countsByYear W23359920792023 @default.
- W2335992079 crossrefType "journal-article" @default.
- W2335992079 hasAuthorship W2335992079A5001278291 @default.
- W2335992079 hasAuthorship W2335992079A5009043932 @default.
- W2335992079 hasAuthorship W2335992079A5049932254 @default.
- W2335992079 hasAuthorship W2335992079A5057589578 @default.
- W2335992079 hasAuthorship W2335992079A5059418406 @default.
- W2335992079 hasAuthorship W2335992079A5067359625 @default.
- W2335992079 hasAuthorship W2335992079A5074089741 @default.
- W2335992079 hasAuthorship W2335992079A5079213443 @default.
- W2335992079 hasAuthorship W2335992079A5084740308 @default.
- W2335992079 hasConcept C121332964 @default.
- W2335992079 hasConcept C133571119 @default.
- W2335992079 hasConcept C135788738 @default.
- W2335992079 hasConcept C145148216 @default.
- W2335992079 hasConcept C147597530 @default.
- W2335992079 hasConcept C147789679 @default.
- W2335992079 hasConcept C156911925 @default.
- W2335992079 hasConcept C178790620 @default.
- W2335992079 hasConcept C179104552 @default.
- W2335992079 hasConcept C185592680 @default.
- W2335992079 hasConcept C201194858 @default.
- W2335992079 hasConcept C21951064 @default.
- W2335992079 hasConcept C2778468930 @default.
- W2335992079 hasConcept C2779281246 @default.
- W2335992079 hasConcept C3288061 @default.
- W2335992079 hasConcept C502696234 @default.
- W2335992079 hasConcept C55493867 @default.
- W2335992079 hasConcept C71240020 @default.
- W2335992079 hasConcept C8010536 @default.
- W2335992079 hasConcept C97355855 @default.
- W2335992079 hasConceptScore W2335992079C121332964 @default.
- W2335992079 hasConceptScore W2335992079C133571119 @default.
- W2335992079 hasConceptScore W2335992079C135788738 @default.
- W2335992079 hasConceptScore W2335992079C145148216 @default.
- W2335992079 hasConceptScore W2335992079C147597530 @default.