FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2336006626> ?p ?o ?g. }

• W2336006626 endingPage "7707" @default.
• W2336006626 startingPage "7702" @default.
• W2336006626 abstract "Abstract The reduction of [Cp′′′Ni(η 3 ‐P 3 )] ( 1 ; Cp′′′=η 5 ‐1,2,4‐ t Bu 3 C 5 H 2 ) with potassium produces the complex anion [(Cp′′′Ni) 2 (μ,η 2:2 ‐P 8 )] 2− ( 2 ), which contains a realgar‐like P 8 unit. The anionic triple‐decker sandwich complex [(Cp′′′Ni) 2 (μ,η 3:3 ‐P 3 )] − ( 3 ) with a cyclo‐P 3 middle deck is obtained when 1 is treated with NaNH 2 as a nucleophile. Na[ 3 ] can subsequently be oxidized with AgOTf to the neutral triple‐decker complex [(Cp′′′Ni) 2 (μ,η 3:3 ‐P 3 )] ( 4 ). In contrast, 1 reacts with LiPPh 2 to give the anionic compound [(Cp′′′Ni) 2 (μ,η 2:2 ‐P 6 PPh 2 )] − ( 5 ), a complex containing a bicyclic P 7 fragment capped by two Cp′′′Ni units. Protonation of Li[ 5 ] with HBF 4 leads to the neutral complex [(Cp′′′Ni) 2 (μ,η 2:2 ‐(HP 6 PPh 2 )] ( 6 ). Adding LiNMe 2 to 1 results in [Cp′′′Ni(η 2 ‐P 3 NMe 2 )] − ( 7 ) becoming accessible, a complex which forms as a result of nucleophilic attack at the cyclo‐P 3 ring of 1 . The complexes K 2 [ 2 ], Na[ 3 ], 4 , 6 , and Li[ 7 ] were fully characterized and their structures determined by single‐crystal X‐ray diffraction." @default.
• W2336006626 created "2016-06-24" @default.
• W2336006626 creator A5019173618 @default.
• W2336006626 creator A5035963991 @default.
• W2336006626 creator A5041573362 @default.
• W2336006626 creator A5091042657 @default.
• W2336006626 date "2016-04-21" @default.
• W2336006626 modified "2023-10-09" @default.
• W2336006626 title "Unexpected Reactivity of [(η⁵-1,2,4-<i>t</i>Bu₃C₅H₂)Ni(η³-P₃)] towards Main Group Nucleophiles and by Reduction" @default.
• W2336006626 cites W1975036248 @default.
• W2336006626 cites W1977075425 @default.
• W2336006626 cites W1985292826 @default.
• W2336006626 cites W1989066978 @default.
• W2336006626 cites W1993137144 @default.
• W2336006626 cites W1999279212 @default.
• W2336006626 cites W1999751891 @default.
• W2336006626 cites W2011330047 @default.
• W2336006626 cites W2012455769 @default.
• W2336006626 cites W2015946675 @default.
• W2336006626 cites W2019868148 @default.
• W2336006626 cites W2020571871 @default.
• W2336006626 cites W2023408524 @default.
• W2336006626 cites W2025238416 @default.
• W2336006626 cites W2029225109 @default.
• W2336006626 cites W2029473995 @default.
• W2336006626 cites W2029500488 @default.
• W2336006626 cites W2032445752 @default.
• W2336006626 cites W2038871458 @default.
• W2336006626 cites W2040274556 @default.
• W2336006626 cites W2044562230 @default.
• W2336006626 cites W2054183877 @default.
• W2336006626 cites W2054343044 @default.
• W2336006626 cites W2056287237 @default.
• W2336006626 cites W2063822957 @default.
• W2336006626 cites W2080978319 @default.
• W2336006626 cites W2085345596 @default.
• W2336006626 cites W2087019653 @default.
• W2336006626 cites W2087232030 @default.
• W2336006626 cites W2091310840 @default.
• W2336006626 cites W2096465893 @default.
• W2336006626 cites W2108229477 @default.
• W2336006626 cites W2115627061 @default.
• W2336006626 cites W2115699186 @default.
• W2336006626 cites W2116938372 @default.
• W2336006626 cites W2122060806 @default.
• W2336006626 cites W2125259530 @default.
• W2336006626 cites W2128474492 @default.
• W2336006626 cites W2129418872 @default.
• W2336006626 cites W2132916274 @default.
• W2336006626 cites W2143266554 @default.
• W2336006626 cites W2156325151 @default.
• W2336006626 cites W2158342328 @default.
• W2336006626 cites W2162554669 @default.
• W2336006626 cites W2275157626 @default.
• W2336006626 cites W2276962377 @default.
• W2336006626 cites W2323435594 @default.
• W2336006626 cites W2337919026 @default.
• W2336006626 cites W2412108804 @default.
• W2336006626 cites W2499949871 @default.
• W2336006626 cites W3005038003 @default.
• W2336006626 cites W4239814050 @default.
• W2336006626 doi "https://doi.org/10.1002/anie.201601775" @default.
• W2336006626 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27097602" @default.
• W2336006626 hasPublicationYear "2016" @default.
• W2336006626 type Work @default.
• W2336006626 sameAs 2336006626 @default.
• W2336006626 citedByCount "38" @default.
• W2336006626 countsByYear W23360066262016 @default.
• W2336006626 countsByYear W23360066262017 @default.
• W2336006626 countsByYear W23360066262018 @default.
• W2336006626 countsByYear W23360066262019 @default.
• W2336006626 countsByYear W23360066262020 @default.
• W2336006626 countsByYear W23360066262021 @default.
• W2336006626 countsByYear W23360066262022 @default.
• W2336006626 countsByYear W23360066262023 @default.
• W2336006626 crossrefType "journal-article" @default.
• W2336006626 hasAuthorship W2336006626A5019173618 @default.
• W2336006626 hasAuthorship W2336006626A5035963991 @default.
• W2336006626 hasAuthorship W2336006626A5041573362 @default.
• W2336006626 hasAuthorship W2336006626A5091042657 @default.
• W2336006626 hasConcept C115624301 @default.
• W2336006626 hasConcept C142724271 @default.
• W2336006626 hasConcept C145148216 @default.
• W2336006626 hasConcept C155647269 @default.
• W2336006626 hasConcept C161790260 @default.
• W2336006626 hasConcept C178790620 @default.
• W2336006626 hasConcept C178907741 @default.
• W2336006626 hasConcept C185592680 @default.
• W2336006626 hasConcept C204787440 @default.
• W2336006626 hasConcept C24961977 @default.
• W2336006626 hasConcept C2776910235 @default.
• W2336006626 hasConcept C30095370 @default.
• W2336006626 hasConcept C55493867 @default.
• W2336006626 hasConcept C71240020 @default.
• W2336006626 hasConcept C71924100 @default.
• W2336006626 hasConcept C8010536 @default.
• W2336006626 hasConceptScore W2336006626C115624301 @default.
• W2336006626 hasConceptScore W2336006626C142724271 @default.

• next