FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2336623591> ?p ?o ?g. }

• W2336623591 endingPage "126" @default.
• W2336623591 startingPage "118" @default.
• W2336623591 abstract "The solvation effects observed in water-organic solutions were studied by combining data for reaction kinetics and dissolution equilibria by means of a linear free-energy (similarity) analysis. Kinetic data for the pH-independent hydrolysis of (4-methoxyphenyl)-2,2-dichloroacetate measured in this work and solubility data for naphthalene, and other substrates of low polarity, in aqueous binary mixtures of methanol, ethanol, acetonitrile, dimethyl sulfoxide (DMSO), and 1,4-dioxane were used. Linear similarity relationships were discovered for these data over the full range of solvent compositions studied. To gain insight into the similarities observed between these different phenomena, molecular dynamics simulations were carried out for naphthalene and an ester in water–acetonitrile solutions. The results revealed considerable preferential solvation of these substrates by the co-solvent. Linear relationships between the experimental data and the mole fractions of acetonitrile in the solvation shells of substrates were found. Surprisingly, a linear relationship was found between the mole fractions of acetonitrile in the solvation shells of the ester and naphthalene. This linearity indicated that a similar solvation mechanism governs even such different phenomena as dissolution and reaction kinetics. The relationships between the experimental data and the results of the molecular dynamics calculations found in this work explained the solvent effect observed in water-organic solutions on the molecular level. Copyright © 2015 John Wiley & Sons, Ltd." @default.
• W2336623591 created "2016-06-24" @default.
• W2336623591 creator A5007756938 @default.
• W2336623591 creator A5011076689 @default.
• W2336623591 creator A5013771575 @default.
• W2336623591 creator A5023019390 @default.
• W2336623591 creator A5023733367 @default.
• W2336623591 creator A5077524523 @default.
• W2336623591 creator A5085865486 @default.
• W2336623591 date "2015-10-19" @default.
• W2336623591 modified "2023-09-27" @default.
• W2336623591 title "Reaction kinetics and solubility in water-organic binary solutions are governed by similar solvation equilibria" @default.
• W2336623591 cites W1966078827 @default.
• W2336623591 cites W1966928360 @default.
• W2336623591 cites W1979943956 @default.
• W2336623591 cites W1983814181 @default.
• W2336623591 cites W1990506949 @default.
• W2336623591 cites W1990939672 @default.
• W2336623591 cites W1997233859 @default.
• W2336623591 cites W2002561733 @default.
• W2336623591 cites W2007825458 @default.
• W2336623591 cites W2009763863 @default.
• W2336623591 cites W2014867746 @default.
• W2336623591 cites W2015898631 @default.
• W2336623591 cites W2027223070 @default.
• W2336623591 cites W2032805074 @default.
• W2336623591 cites W2034982523 @default.
• W2336623591 cites W2035266068 @default.
• W2336623591 cites W2037788435 @default.
• W2336623591 cites W2040058920 @default.
• W2336623591 cites W2045076102 @default.
• W2336623591 cites W2047874363 @default.
• W2336623591 cites W2049475242 @default.
• W2336623591 cites W2079167271 @default.
• W2336623591 cites W2081693079 @default.
• W2336623591 cites W2085930485 @default.
• W2336623591 cites W2087630698 @default.
• W2336623591 cites W2103734924 @default.
• W2336623591 cites W2107977883 @default.
• W2336623591 cites W2114460104 @default.
• W2336623591 cites W2115892857 @default.
• W2336623591 cites W2120707054 @default.
• W2336623591 cites W2128572087 @default.
• W2336623591 cites W2149397893 @default.
• W2336623591 cites W2158468933 @default.
• W2336623591 cites W2324145887 @default.
• W2336623591 cites W2327865522 @default.
• W2336623591 cites W2502341799 @default.
• W2336623591 cites W4249770194 @default.
• W2336623591 cites W4255699687 @default.
• W2336623591 cites W585575871 @default.
• W2336623591 doi "https://doi.org/10.1002/poc.3507" @default.
• W2336623591 hasPublicationYear "2015" @default.
• W2336623591 type Work @default.
• W2336623591 sameAs 2336623591 @default.
• W2336623591 citedByCount "3" @default.
• W2336623591 countsByYear W23366235912016 @default.
• W2336623591 countsByYear W23366235912018 @default.
• W2336623591 countsByYear W23366235912022 @default.
• W2336623591 crossrefType "journal-article" @default.
• W2336623591 hasAuthorship W2336623591A5007756938 @default.
• W2336623591 hasAuthorship W2336623591A5011076689 @default.
• W2336623591 hasAuthorship W2336623591A5013771575 @default.
• W2336623591 hasAuthorship W2336623591A5023019390 @default.
• W2336623591 hasAuthorship W2336623591A5023733367 @default.
• W2336623591 hasAuthorship W2336623591A5077524523 @default.
• W2336623591 hasAuthorship W2336623591A5085865486 @default.
• W2336623591 hasConcept C121332964 @default.
• W2336623591 hasConcept C132439834 @default.
• W2336623591 hasConcept C147597530 @default.
• W2336623591 hasConcept C147789679 @default.
• W2336623591 hasConcept C148093993 @default.
• W2336623591 hasConcept C149823470 @default.
• W2336623591 hasConcept C155574463 @default.
• W2336623591 hasConcept C178790620 @default.
• W2336623591 hasConcept C179104552 @default.
• W2336623591 hasConcept C184651966 @default.
• W2336623591 hasConcept C185592680 @default.
• W2336623591 hasConcept C2777463227 @default.
• W2336623591 hasConcept C2780471494 @default.
• W2336623591 hasConcept C36591836 @default.
• W2336623591 hasConcept C88380143 @default.
• W2336623591 hasConcept C97355855 @default.
• W2336623591 hasConceptScore W2336623591C121332964 @default.
• W2336623591 hasConceptScore W2336623591C132439834 @default.
• W2336623591 hasConceptScore W2336623591C147597530 @default.
• W2336623591 hasConceptScore W2336623591C147789679 @default.
• W2336623591 hasConceptScore W2336623591C148093993 @default.
• W2336623591 hasConceptScore W2336623591C149823470 @default.
• W2336623591 hasConceptScore W2336623591C155574463 @default.
• W2336623591 hasConceptScore W2336623591C178790620 @default.
• W2336623591 hasConceptScore W2336623591C179104552 @default.
• W2336623591 hasConceptScore W2336623591C184651966 @default.
• W2336623591 hasConceptScore W2336623591C185592680 @default.
• W2336623591 hasConceptScore W2336623591C2777463227 @default.
• W2336623591 hasConceptScore W2336623591C2780471494 @default.
• W2336623591 hasConceptScore W2336623591C36591836 @default.
• W2336623591 hasConceptScore W2336623591C88380143 @default.

• next