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- W2336698723 abstract "Solvent and electrode kinetic effects on the anodic oxidation of Br - -Br 3 - -Br 2 system involving Br - /Br 3 - and Br 3 - /Br 2 redox couples, have been studied on bare and platinized Pt and C surfaces by cyclic voltammetric (CV) measurements in some dipolar aportic solvents like acetonitrile, N,N-dimethylformamide and propylene carbonate and in water on bright Pt surface. The rate constants (k S ) have been evaluated by Shain and Nicholson's formulations as appropriate to the irreversible and quasi-reversible CV waves observed in different cases. Kinetic solvent effects on both the redox reactions on Pt surface in different solvents have been analyzed in the light of initial and transition state (TS) solvation using the previously determined solvation free energies of Br - , Br 3 - and Br 2 in the respective solvents. The observed k s values for both the redox couples reflect that the electrocatalytic activities of the electrodes are in the order C < Pt < (Pt) Pt < (C)Pt, as are expected from the combined effects of geometric and electronic characters of the involved electrode surfaces." @default.
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- W2336698723 date "2003-10-01" @default.
- W2336698723 modified "2023-10-17" @default.
- W2336698723 title "Solvent and electrode kinetic effects on anodic oxidation of Br--Br3--Br2 system on some bare and platinized electrode in some dipolar aprotic solvents from cyclic voltammetric measurements" @default.
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