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• W2336720678 abstract "Abstract Polarized absorption spectra of f-f absorption bands 4 I 9/2  →  4 ( F 7/2  +  S 3/2 ) and ( 4 G 9/2  +  2 K 13/2  +  4 G 7/2 ) in the Nd 3+ ion in the Nd 0.5 Gd 0.5 Fe 3 (BO 3 ) 4 single crystal were studied as a function of temperature in the range of 2–40 K and as a function of magnetic field in the range of 0–65 kOe at 2 K. It was found out that the selection rules for f-f electron transitions substantially changed in the magnetically ordered state of the crystal, and they strongly depended on the orientation of the Fe and Nd ions magnetic moments relative to the light polarization. The splitting of the excited states of the Nd 3+ ion in the exchange field of the Fe sublattice were determined. It was revealed that the value of the exchange splitting (the exchange interaction) did not correlate with the theoretical Lande factor. The Lande factors of the excited states were experimentally found. The local reorientation field induced metamagnetic transitions were observed in the excited states. In some excited states the energetically favorable orientation of the Nd 3+ ion magnetic moment is opposite to that in the ground state." @default.
• W2336720678 created "2016-06-24" @default.
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• W2336720678 date "2016-09-01" @default.
• W2336720678 modified "2023-09-24" @default.
• W2336720678 title "Peculiarities of magnetic properties of Nd3+ ions in the Nd0.5Gd0.5Fe3(BO3)4 crystal in the optically excited states 4(F7/2 + S3/2) and (4G9/2 + 2K13/2 + 4G7/2)" @default.
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• W2336720678 doi "https://doi.org/10.1016/j.jallcom.2016.04.088" @default.
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