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- W2336726051 abstract "Die Reduktion des Androstadiendions (I) bei tiefen Temp. in Gegenwart von Methylcyclopentan (Mcp) als Wasserstoff-Quelle in einem stark sauren Medium aus HF/ SbFs verläuft unter Umlagerung zu den Diketonen (II)-(IV);die Produktverteilung varii mit der Temp. und Acidität. Analoge Reduktion der l4-C-Epimeren (II) bzw. (V) liefert erst nach 16 h Reaktionsdauer die Ketone (IV) (und 15% eines Gemisches zweier Verbindungen, von denen eine wahrscheinlich das 14-C-Epimere des Spirans (III) ist) bzw. (III) und (IV)." @default.
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- W2336726051 date "1980-02-05" @default.
- W2336726051 modified "2023-10-14" @default.
- W2336726051 title "ChemInform Abstract: LOW TEMPERATURE REDUCTION OF UNSATURATED STEROIDAL KETONES IN SUPERACIDIC MEDIA" @default.
- W2336726051 doi "https://doi.org/10.1002/chin.198005349" @default.
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