Matches in SemOpenAlex for { <https://semopenalex.org/work/W2336757777> ?p ?o ?g. }
- W2336757777 endingPage "5526" @default.
- W2336757777 startingPage "5523" @default.
- W2336757777 abstract "Absolute pKas of selected salts with different counter-anions were measured with high precision in four aprotic ionic liquids (AILs), which enables a detailed examination of solvation effect of ILs on salts. Interestingly, the counter-anions of the ylide precursor salts, protic amine, and phenol salts of this study, though differing dramatically in size and electron dispersion, were found to have no effect on the respective pKas of the substrates. This indicates that the ionic species generated upon acidic dissociation of the salts in weakly polar AILs of low dielectric constant (ε: 10-15) are not ion-paired, or in other words, behave like free ions as if in strongly dissociating molecular solvents of high polarity (e.g., DMSO). This suggests that the widely assumed ion-pairing phenomenon, an issue of much debate, is not important in the AILs under our experimental conditions, presenting a typical ionic-liquid effect on the solvation of charged species in AILs." @default.
- W2336757777 created "2016-06-24" @default.
- W2336757777 creator A5013291885 @default.
- W2336757777 creator A5044435921 @default.
- W2336757777 creator A5054631829 @default.
- W2336757777 creator A5060551376 @default.
- W2336757777 creator A5065058975 @default.
- W2336757777 date "2016-04-20" @default.
- W2336757777 modified "2023-10-18" @default.
- W2336757777 title "Weakly Polar Aprotic Ionic Liquids Acting as Strong Dissociating Solvent: A Typical “Ionic Liquid Effect” Revealed by Accurate Measurement of Absolute p<i>K</i><sub>a</sub> of Ylide Precursor Salts" @default.
- W2336757777 cites W1897447826 @default.
- W2336757777 cites W1965324518 @default.
- W2336757777 cites W1966632784 @default.
- W2336757777 cites W1968479888 @default.
- W2336757777 cites W1968553589 @default.
- W2336757777 cites W1982479518 @default.
- W2336757777 cites W1983324291 @default.
- W2336757777 cites W2000072994 @default.
- W2336757777 cites W2005307077 @default.
- W2336757777 cites W2005725452 @default.
- W2336757777 cites W2011021948 @default.
- W2336757777 cites W2012429772 @default.
- W2336757777 cites W2020215343 @default.
- W2336757777 cites W2020345275 @default.
- W2336757777 cites W2021678689 @default.
- W2336757777 cites W2032014175 @default.
- W2336757777 cites W2032732317 @default.
- W2336757777 cites W2038263752 @default.
- W2336757777 cites W2041193862 @default.
- W2336757777 cites W2042083742 @default.
- W2336757777 cites W2048240070 @default.
- W2336757777 cites W2063217685 @default.
- W2336757777 cites W2064572842 @default.
- W2336757777 cites W2083031164 @default.
- W2336757777 cites W2093442613 @default.
- W2336757777 cites W2129627646 @default.
- W2336757777 cites W2137736081 @default.
- W2336757777 cites W2153772742 @default.
- W2336757777 cites W2156538456 @default.
- W2336757777 cites W2263759338 @default.
- W2336757777 cites W2316385519 @default.
- W2336757777 cites W2322331084 @default.
- W2336757777 cites W2323116490 @default.
- W2336757777 cites W2325001308 @default.
- W2336757777 cites W2339209075 @default.
- W2336757777 cites W2949085115 @default.
- W2336757777 cites W2951059818 @default.
- W2336757777 cites W2952317623 @default.
- W2336757777 cites W4238323281 @default.
- W2336757777 doi "https://doi.org/10.1021/jacs.6b02607" @default.
- W2336757777 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27077218" @default.
- W2336757777 hasPublicationYear "2016" @default.
- W2336757777 type Work @default.
- W2336757777 sameAs 2336757777 @default.
- W2336757777 citedByCount "42" @default.
- W2336757777 countsByYear W23367577772016 @default.
- W2336757777 countsByYear W23367577772017 @default.
- W2336757777 countsByYear W23367577772018 @default.
- W2336757777 countsByYear W23367577772019 @default.
- W2336757777 countsByYear W23367577772020 @default.
- W2336757777 countsByYear W23367577772021 @default.
- W2336757777 countsByYear W23367577772022 @default.
- W2336757777 countsByYear W23367577772023 @default.
- W2336757777 crossrefType "journal-article" @default.
- W2336757777 hasAuthorship W2336757777A5013291885 @default.
- W2336757777 hasAuthorship W2336757777A5044435921 @default.
- W2336757777 hasAuthorship W2336757777A5054631829 @default.
- W2336757777 hasAuthorship W2336757777A5060551376 @default.
- W2336757777 hasAuthorship W2336757777A5065058975 @default.
- W2336757777 hasConcept C121332964 @default.
- W2336757777 hasConcept C1276947 @default.
- W2336757777 hasConcept C145148216 @default.
- W2336757777 hasConcept C147597530 @default.
- W2336757777 hasConcept C147789679 @default.
- W2336757777 hasConcept C148093993 @default.
- W2336757777 hasConcept C154881586 @default.
- W2336757777 hasConcept C161790260 @default.
- W2336757777 hasConcept C178790620 @default.
- W2336757777 hasConcept C179104552 @default.
- W2336757777 hasConcept C184651966 @default.
- W2336757777 hasConcept C185592680 @default.
- W2336757777 hasConcept C2182769 @default.
- W2336757777 hasConcept C22163223 @default.
- W2336757777 hasConcept C2780471494 @default.
- W2336757777 hasConcept C29705727 @default.
- W2336757777 hasConcept C32909587 @default.
- W2336757777 hasConcept C61978335 @default.
- W2336757777 hasConceptScore W2336757777C121332964 @default.
- W2336757777 hasConceptScore W2336757777C1276947 @default.
- W2336757777 hasConceptScore W2336757777C145148216 @default.
- W2336757777 hasConceptScore W2336757777C147597530 @default.
- W2336757777 hasConceptScore W2336757777C147789679 @default.
- W2336757777 hasConceptScore W2336757777C148093993 @default.
- W2336757777 hasConceptScore W2336757777C154881586 @default.
- W2336757777 hasConceptScore W2336757777C161790260 @default.
- W2336757777 hasConceptScore W2336757777C178790620 @default.
- W2336757777 hasConceptScore W2336757777C179104552 @default.
- W2336757777 hasConceptScore W2336757777C184651966 @default.