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- W2336956714 abstract "Mitomycin A (C16H19O6N3) and mitomycin C (C15H18O5N4) are pigments which have the quinoid structure. When treated with aqueous ammonia, mitomycin A is converted to mitomycin C. Acid hydrolysis of mitomycin C gave three degradation products, namely, C14H15O5N4, C14H15O6N3 and C13H14O5N2. Acetylation with acetic anhydride and pyridine and methylation with methyl iodide gave monoacetyl and monomethyl derivatives of mitomycin C respectively, though diacetate of demethyl derivatives were obtained when boiled with acetic anhydride. The structure of mitomycinone (C13H14O5N2) obtained by acid hydrolysis of mitomycins was studied. It was confirmed that mitomycinone contained 2 or 3-hydroxymethyl-6-methyl-5-hydroxylindolequinone (4,7) in its structure." @default.
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- W2336956714 date "1964-06-01" @default.
- W2336956714 modified "2023-09-25" @default.
- W2336956714 title "Studies on Mitomycins, Carcinostatic Antibiotics" @default.
- W2336956714 doi "https://doi.org/10.1080/00021369.1964.10858249" @default.
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